In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

Nethmi De Alwis Watuthanthrige; Michael L. Allegrezza; Madison T. Dolan; Alex J. Kloster; Marina Kovaliov; Saadyah Averick; Dominik Konkolewicz

doi:10.1002/anie.201905317

In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

Nethmi De Alwis Watuthanthrige
, Michael L. Allegrezza
, Madison T. Dolan
, Alex J. Kloster
, Marina Kovaliov
, Saadyah Averick
, Dominik Konkolewicz

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.

Original language	English
Pages (from-to)	11826-11829
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	34
DOIs	https://doi.org/10.1002/anie.201905317
State	Published - 19 Aug 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

We are grateful to Theresa Ramelot for experimental assistance. This work was supported by institutional funds at Miami University.

Funders
University of Miami

Keywords

Chemiluminescence
Kinetics
Photochemistry
Photopolymerization
Reversible addition–fragmentation chain transfer polymerization

Access to Document

10.1002/anie.201905317

Cite this

@article{03f5c43cfda142dcaa47e78b6a402058,

title = "In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization",

abstract = "The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.",

keywords = "Chemiluminescence, Kinetics, Photochemistry, Photopolymerization, Reversible addition–fragmentation chain transfer polymerization",

author = "\{De Alwis Watuthanthrige\}, Nethmi and Allegrezza, \{Michael L.\} and Dolan, \{Madison T.\} and Kloster, \{Alex J.\} and Marina Kovaliov and Saadyah Averick and Dominik Konkolewicz",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = aug,

day = "19",

doi = "10.1002/anie.201905317",

language = "אנגלית",

volume = "58",

pages = "11826--11829",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "34",

}

TY - JOUR

T1 - In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

AU - De Alwis Watuthanthrige, Nethmi

AU - Allegrezza, Michael L.

AU - Dolan, Madison T.

AU - Kloster, Alex J.

AU - Kovaliov, Marina

AU - Averick, Saadyah

AU - Konkolewicz, Dominik

PY - 2019/8/19

Y1 - 2019/8/19

N2 - The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.

AB - The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.

KW - Chemiluminescence

KW - Kinetics

KW - Photochemistry

KW - Photopolymerization

KW - Reversible addition–fragmentation chain transfer polymerization

UR - https://www.scopus.com/pages/publications/85069870357

U2 - 10.1002/anie.201905317

DO - 10.1002/anie.201905317

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

C2 - 31211522

AN - SCOPUS:85069870357

SN - 1433-7851

VL - 58

SP - 11826

EP - 11829

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 34

ER -

In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

Abstract

Bibliographical note

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this