In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

Nethmi De Alwis Watuthanthrige; Michael L. Allegrezza; Madison T. Dolan; Alex J. Kloster; Marina Kovaliov; Saadyah Averick; Dominik Konkolewicz

doi:10.1002/anie.201905317

In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

Nethmi De Alwis Watuthanthrige, Michael L. Allegrezza, Madison T. Dolan, Alex J. Kloster, Marina Kovaliov, Saadyah Averick, Dominik Konkolewicz

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.

Original language	English
Pages (from-to)	11826-11829
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	58
Issue number	34
DOIs	https://doi.org/10.1002/anie.201905317
State	Published - 19 Aug 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

We are grateful to Theresa Ramelot for experimental assistance. This work was supported by institutional funds at Miami University.

Funders	Funder number
University of Miami

Keywords

Chemiluminescence
Kinetics
Photochemistry
Photopolymerization
Reversible addition–fragmentation chain transfer polymerization

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10.1002/anie.201905317

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abstract = "The power of chemical light generation (chemiluminescence) is used to drive polymerization reactions. A biphasic reaction is developed such that light-generating reactions are confined to the organic phase and photopolymerization occurs in the aqueous phase. Well-defined RAFT-capped polymers are synthesized and the kinetics are shown to be dictated by light generation.",

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AU - Kloster, Alex J.

AU - Kovaliov, Marina

AU - Averick, Saadyah

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In-situ Chemiluminescence-Driven Reversible Addition–Fragmentation Chain-Transfer Photopolymerization

Abstract

Bibliographical note

Funding

Keywords

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