Improvement of magnetic and ferroelectric properties of BiFeO3 nanoparticles on Tb and Co substitution

A. Das; S. De; S. Bandyopadhyay; S. Chatterjee; D. Das

doi:10.1063/1.4946695

Improvement of magnetic and ferroelectric properties of BiFeO₃ nanoparticles on Tb and Co substitution

A. Das
, S. De
, S. Bandyopadhyay
, S. Chatterjee
, D. Das

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

Tb and Co substituted bismuth ferrite nanoparticles (NPs) with chemical composition Bi_1-xTb_xFe_1-yCo_yO₃ (x = 0, 0.05; y = 0, 0.05) have been synthesized by a sol-gel method and characterized by x-ray diffraction (XRD), Mossbauer spectroscopy, dc magnetization and electric polarization measurements. The aim of the present work is to improve ferroelectric properties of BiFeO₃ by substitution of Tb³⁺ ions in Bi³⁺ site and magnetic properties by substitution of Co²⁺ in Fe³⁺ site. The XRD patterns of all prepared samples show formation of the desired phase along with a small amount of impurity. Room temperature Mossbauer spectroscopic studies reveal that all samples are in magnetically ordered state. Magnetic hysteresis loops of all samples indicate a significant enhancement of magnetic moment and coercivity whereas electric polarization measurements at room temperature reveal an improvement of ferroelectric properties in the co-substituted sample.

Original language	English
Title of host publication	International Conference on Condensed Matter and Applied Physics, ICC 2015
Subtitle of host publication	Proceeding of International Conference on Condensed Matter and Applied Physics
Editors	Manoj Singh Shekhawat, Sudhir Bhardwaj, Bhuvneshwer Suthar
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735413757
DOIs	https://doi.org/10.1063/1.4946695
State	Published - 6 May 2016
Externally published	Yes
Event	International Conference on Condensed Matter and Applied Physics, ICC 2015 - Bikaner, India Duration: 30 Oct 2015 → 31 Oct 2015

Publication series

Name	AIP Conference Proceedings
Volume	1728
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	International Conference on Condensed Matter and Applied Physics, ICC 2015
Country/Territory	India
City	Bikaner
Period	30/10/15 → 31/10/15

Bibliographical note

Publisher Copyright:
© 2016 Author(s).

Access to Document

10.1063/1.4946695

Cite this

Das, A., De, S., Bandyopadhyay, S., Chatterjee, S., & Das, D. (2016). Improvement of magnetic and ferroelectric properties of BiFeO₃ nanoparticles on Tb and Co substitution. In M. S. Shekhawat, S. Bhardwaj, & B. Suthar (Eds.), International Conference on Condensed Matter and Applied Physics, ICC 2015: Proceeding of International Conference on Condensed Matter and Applied Physics Article 020644 (AIP Conference Proceedings; Vol. 1728). American Institute of Physics Inc.. https://doi.org/10.1063/1.4946695

Das, A. ; De, S. ; Bandyopadhyay, S. et al. / Improvement of magnetic and ferroelectric properties of BiFeO₃ nanoparticles on Tb and Co substitution. International Conference on Condensed Matter and Applied Physics, ICC 2015: Proceeding of International Conference on Condensed Matter and Applied Physics. editor / Manoj Singh Shekhawat ; Sudhir Bhardwaj ; Bhuvneshwer Suthar. American Institute of Physics Inc., 2016. (AIP Conference Proceedings).

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title = "Improvement of magnetic and ferroelectric properties of BiFeO3 nanoparticles on Tb and Co substitution",

abstract = "Tb and Co substituted bismuth ferrite nanoparticles (NPs) with chemical composition Bi1-xTbxFe1-yCoyO3 (x = 0, 0.05; y = 0, 0.05) have been synthesized by a sol-gel method and characterized by x-ray diffraction (XRD), Mossbauer spectroscopy, dc magnetization and electric polarization measurements. The aim of the present work is to improve ferroelectric properties of BiFeO3 by substitution of Tb3+ ions in Bi3+ site and magnetic properties by substitution of Co2+ in Fe3+ site. The XRD patterns of all prepared samples show formation of the desired phase along with a small amount of impurity. Room temperature Mossbauer spectroscopic studies reveal that all samples are in magnetically ordered state. Magnetic hysteresis loops of all samples indicate a significant enhancement of magnetic moment and coercivity whereas electric polarization measurements at room temperature reveal an improvement of ferroelectric properties in the co-substituted sample.",

author = "A. Das and S. De and S. Bandyopadhyay and S. Chatterjee and D. Das",

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Das, A, De, S, Bandyopadhyay, S, Chatterjee, S & Das, D 2016, Improvement of magnetic and ferroelectric properties of BiFeO₃ nanoparticles on Tb and Co substitution. in MS Shekhawat, S Bhardwaj & B Suthar (eds), International Conference on Condensed Matter and Applied Physics, ICC 2015: Proceeding of International Conference on Condensed Matter and Applied Physics., 020644, AIP Conference Proceedings, vol. 1728, American Institute of Physics Inc., International Conference on Condensed Matter and Applied Physics, ICC 2015, Bikaner, India, 30/10/15. https://doi.org/10.1063/1.4946695

Improvement of magnetic and ferroelectric properties of BiFeO₃ nanoparticles on Tb and Co substitution. / Das, A.; De, S.; Bandyopadhyay, S. et al.
International Conference on Condensed Matter and Applied Physics, ICC 2015: Proceeding of International Conference on Condensed Matter and Applied Physics. ed. / Manoj Singh Shekhawat; Sudhir Bhardwaj; Bhuvneshwer Suthar. American Institute of Physics Inc., 2016. 020644 (AIP Conference Proceedings; Vol. 1728).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Das, D.

PY - 2016/5/6

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N2 - Tb and Co substituted bismuth ferrite nanoparticles (NPs) with chemical composition Bi1-xTbxFe1-yCoyO3 (x = 0, 0.05; y = 0, 0.05) have been synthesized by a sol-gel method and characterized by x-ray diffraction (XRD), Mossbauer spectroscopy, dc magnetization and electric polarization measurements. The aim of the present work is to improve ferroelectric properties of BiFeO3 by substitution of Tb3+ ions in Bi3+ site and magnetic properties by substitution of Co2+ in Fe3+ site. The XRD patterns of all prepared samples show formation of the desired phase along with a small amount of impurity. Room temperature Mossbauer spectroscopic studies reveal that all samples are in magnetically ordered state. Magnetic hysteresis loops of all samples indicate a significant enhancement of magnetic moment and coercivity whereas electric polarization measurements at room temperature reveal an improvement of ferroelectric properties in the co-substituted sample.

AB - Tb and Co substituted bismuth ferrite nanoparticles (NPs) with chemical composition Bi1-xTbxFe1-yCoyO3 (x = 0, 0.05; y = 0, 0.05) have been synthesized by a sol-gel method and characterized by x-ray diffraction (XRD), Mossbauer spectroscopy, dc magnetization and electric polarization measurements. The aim of the present work is to improve ferroelectric properties of BiFeO3 by substitution of Tb3+ ions in Bi3+ site and magnetic properties by substitution of Co2+ in Fe3+ site. The XRD patterns of all prepared samples show formation of the desired phase along with a small amount of impurity. Room temperature Mossbauer spectroscopic studies reveal that all samples are in magnetically ordered state. Magnetic hysteresis loops of all samples indicate a significant enhancement of magnetic moment and coercivity whereas electric polarization measurements at room temperature reveal an improvement of ferroelectric properties in the co-substituted sample.

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Das A, De S, Bandyopadhyay S, Chatterjee S, Das D. Improvement of magnetic and ferroelectric properties of BiFeO₃ nanoparticles on Tb and Co substitution. In Shekhawat MS, Bhardwaj S, Suthar B, editors, International Conference on Condensed Matter and Applied Physics, ICC 2015: Proceeding of International Conference on Condensed Matter and Applied Physics. American Institute of Physics Inc. 2016. 020644. (AIP Conference Proceedings). doi: 10.1063/1.4946695