Identification of Surface Films Formed on Lithium Surfaces in γ-Butyrolactone Solutions: I. Uncontaminated Solutions

Doron Aurbach

doi:10.1149/1.2096977

Identification of Surface Films Formed on Lithium Surfaces in γ-Butyrolactone Solutions: I. Uncontaminated Solutions

Doron Aurbach

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Abstract

Surface films formed on lithium surfaces in γ-butyrolactone (BL) solutions were studied using FTIR and NMR. Two types of lithium surfaces were studied: solid lithium and lithium amalgam. In both cases, the main components of those surface films were lithium butyrate (CH₃CH₂CH₂COOLi) and a lithium salt of a cyclic β-keto ester anion. Their mechanism of formation is discussed.

Original language	English
Pages (from-to)	1606-1610
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	136
Issue number	6
DOIs	https://doi.org/10.1149/1.2096977
State	Published - Jun 1989

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abstract = "Surface films formed on lithium surfaces in γ-butyrolactone (BL) solutions were studied using FTIR and NMR. Two types of lithium surfaces were studied: solid lithium and lithium amalgam. In both cases, the main components of those surface films were lithium butyrate (CH3CH2CH2COOLi) and a lithium salt of a cyclic β-keto ester anion. Their mechanism of formation is discussed.",

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AB - Surface films formed on lithium surfaces in γ-butyrolactone (BL) solutions were studied using FTIR and NMR. Two types of lithium surfaces were studied: solid lithium and lithium amalgam. In both cases, the main components of those surface films were lithium butyrate (CH3CH2CH2COOLi) and a lithium salt of a cyclic β-keto ester anion. Their mechanism of formation is discussed.

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Identification of Surface Films Formed on Lithium Surfaces in γ-Butyrolactone Solutions: I. Uncontaminated Solutions

Abstract

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