Identification of Surface Films Formed on Lithium Surfaces in γ-Butyrolactone Solutions: II. Contaminated Solutions

Doron Aurbach

doi:10.1149/1.2096978

Identification of Surface Films Formed on Lithium Surfaces in γ-Butyrolactone Solutions: II. Contaminated Solutions

Doron Aurbach

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The influence of water, oxygen, and nitrogen contamination on the surface chemistry of lithium in γ-butyrolactone (BL) solutions was studied. Both water and oxygen contamination in BL solutions seem to have a pronounced effect on surface films formed in the Li-BL systems because they react with lithium to form hydroxide or oxides that attack BL nucleophilically. Nitrogen contamination seems to have a marginal (if any) effect on the surface chemistry of the Li-BL system in spite of the fact that BL is reactive with lithium nitride.

Original language	English
Pages (from-to)	1611-1614
Number of pages	4
Journal	Journal of the Electrochemical Society
Volume	136
Issue number	6
DOIs	https://doi.org/10.1149/1.2096978
State	Published - Jun 1989

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abstract = "The influence of water, oxygen, and nitrogen contamination on the surface chemistry of lithium in γ-butyrolactone (BL) solutions was studied. Both water and oxygen contamination in BL solutions seem to have a pronounced effect on surface films formed in the Li-BL systems because they react with lithium to form hydroxide or oxides that attack BL nucleophilically. Nitrogen contamination seems to have a marginal (if any) effect on the surface chemistry of the Li-BL system in spite of the fact that BL is reactive with lithium nitride.",

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Identification of Surface Films Formed on Lithium Surfaces in γ-Butyrolactone Solutions: II. Contaminated Solutions

Abstract

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