TY - JOUR
T1 - Hydrodynamics of reactive systems
T2 - Chemical reactions near the critical points
AU - Gitterman, M.
PY - 2009/4/1
Y1 - 2009/4/1
N2 - The rate of a chemical reaction is expressed in terms of the correlation functions which are found from the full system of hydrodynamic equations in reactive systems. In the limiting cases one obtains all three types of behavior of reaction rates near the critical points found in experiments (slowing-down, speeding-up, insensitivity to criticality). This behavior depends on the number of reactive and inert components in a system, proximity and path of approach to the critical point.
AB - The rate of a chemical reaction is expressed in terms of the correlation functions which are found from the full system of hydrodynamic equations in reactive systems. In the limiting cases one obtains all three types of behavior of reaction rates near the critical points found in experiments (slowing-down, speeding-up, insensitivity to criticality). This behavior depends on the number of reactive and inert components in a system, proximity and path of approach to the critical point.
KW - Chemical reactions
KW - Critical point
KW - Onsager coefficients
UR - http://www.scopus.com/inward/record.url?scp=58549109844&partnerID=8YFLogxK
U2 - 10.1016/j.physa.2008.11.020
DO - 10.1016/j.physa.2008.11.020
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:58549109844
SN - 0378-4371
VL - 388
SP - 1046
EP - 1056
JO - Physica A: Statistical Mechanics and its Applications
JF - Physica A: Statistical Mechanics and its Applications
IS - 7
ER -