HRGO–Co@SnO2 Nanocomposite for Electrochemical Detection of Hydrazine

Subramanian Ramanathan; Elaiyappillai Elanthamilan; Asir Obadiah; Arulappan Durairaj; Palanisamy SanthoshKumar; Johnson Princy Merlin; Subramanian Ramasundaram; Samuel Vasanthkumar

doi:10.1007/s11664-018-6738-z

HRGO–Co@SnO₂ Nanocomposite for Electrochemical Detection of Hydrazine

Subramanian Ramanathan
, Elaiyappillai Elanthamilan
, Asir Obadiah
, Arulappan Durairaj
, Palanisamy SanthoshKumar
, Johnson Princy Merlin
, Subramanian Ramasundaram
, Samuel Vasanthkumar

Karunya University
Bharathidasan University
Sunchon National University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Abstract: A low-cost modified electrode using bimetallic nanoparticles (Co@SnO₂) and honey reduced graphene oxide (HRGO) has been developed for detecting trace amounts of hydrazine. The HRGO and Co@SnO₂ nanoparticles were prepared using a natural reducing agent, honey. The synthesized nanoparticles and nanocomposite (HRGO–Co@SnO₂) were characterized by Fourier transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) studies, scanning electron microscopy (SEM) and Energy dispersive spectroscopic analysis (EDA). The electrocatalytic ability of the modified glassy carbon electrode (GCE) to detect hydrazine was investigated. The modified electrode exhibited a wide linear range of (0–50 μL) to detect hydrazine and had a low detection limit of 10 μL. This modified electrode had superior sensing performance compared to previously reported electrodes and also exhibited good repeatability, reproducibility, stability and ease of operation.

Original language	English
Pages (from-to)	542-550
Number of pages	9
Journal	Journal of Electronic Materials
Volume	48
Issue number	1
DOIs	https://doi.org/10.1007/s11664-018-6738-z
State	Published - 15 Jan 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2018, The Minerals, Metals & Materials Society.

Funding

The authors thank the Management and Administration of Karunya University for their support and help. The authors are grateful to the Department of Science and Technology, Govt. of India, for their financial support.

Funders
Department of Science and Technology, Government of Kerala

Keywords

Hydrazine
bimetallic nanoparticles
honey
honey reduced graphene oxide

Access to Document

10.1007/s11664-018-6738-z

Cite this

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title = "HRGO–Co@SnO2 Nanocomposite for Electrochemical Detection of Hydrazine",

abstract = "Abstract: A low-cost modified electrode using bimetallic nanoparticles (Co@SnO2) and honey reduced graphene oxide (HRGO) has been developed for detecting trace amounts of hydrazine. The HRGO and Co@SnO2 nanoparticles were prepared using a natural reducing agent, honey. The synthesized nanoparticles and nanocomposite (HRGO–Co@SnO2) were characterized by Fourier transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) studies, scanning electron microscopy (SEM) and Energy dispersive spectroscopic analysis (EDA). The electrocatalytic ability of the modified glassy carbon electrode (GCE) to detect hydrazine was investigated. The modified electrode exhibited a wide linear range of (0–50 μL) to detect hydrazine and had a low detection limit of 10 μL. This modified electrode had superior sensing performance compared to previously reported electrodes and also exhibited good repeatability, reproducibility, stability and ease of operation.",

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T1 - HRGO–Co@SnO2 Nanocomposite for Electrochemical Detection of Hydrazine

AU - Ramanathan, Subramanian

AU - Elanthamilan, Elaiyappillai

AU - Obadiah, Asir

AU - Durairaj, Arulappan

AU - SanthoshKumar, Palanisamy

AU - Princy Merlin, Johnson

AU - Ramasundaram, Subramanian

AU - Vasanthkumar, Samuel

PY - 2019/1/15

Y1 - 2019/1/15

N2 - Abstract: A low-cost modified electrode using bimetallic nanoparticles (Co@SnO2) and honey reduced graphene oxide (HRGO) has been developed for detecting trace amounts of hydrazine. The HRGO and Co@SnO2 nanoparticles were prepared using a natural reducing agent, honey. The synthesized nanoparticles and nanocomposite (HRGO–Co@SnO2) were characterized by Fourier transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) studies, scanning electron microscopy (SEM) and Energy dispersive spectroscopic analysis (EDA). The electrocatalytic ability of the modified glassy carbon electrode (GCE) to detect hydrazine was investigated. The modified electrode exhibited a wide linear range of (0–50 μL) to detect hydrazine and had a low detection limit of 10 μL. This modified electrode had superior sensing performance compared to previously reported electrodes and also exhibited good repeatability, reproducibility, stability and ease of operation.

AB - Abstract: A low-cost modified electrode using bimetallic nanoparticles (Co@SnO2) and honey reduced graphene oxide (HRGO) has been developed for detecting trace amounts of hydrazine. The HRGO and Co@SnO2 nanoparticles were prepared using a natural reducing agent, honey. The synthesized nanoparticles and nanocomposite (HRGO–Co@SnO2) were characterized by Fourier transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) studies, scanning electron microscopy (SEM) and Energy dispersive spectroscopic analysis (EDA). The electrocatalytic ability of the modified glassy carbon electrode (GCE) to detect hydrazine was investigated. The modified electrode exhibited a wide linear range of (0–50 μL) to detect hydrazine and had a low detection limit of 10 μL. This modified electrode had superior sensing performance compared to previously reported electrodes and also exhibited good repeatability, reproducibility, stability and ease of operation.

KW - Hydrazine

KW - bimetallic nanoparticles

KW - honey

KW - honey reduced graphene oxide

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