Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

M. Gandelman; D. Milstein

doi:10.1039/b004820h

Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

M. Gandelman
, D. Milstein

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

Reaction of [RhCl(COE)₂]₂ with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H₂ pressure results in selective catalytic activation of an unstrained C-N single bond.

Original language	English
Pages (from-to)	1603-1604
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b004820h
State	Published - 7 Sep 2000
Externally published	Yes

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title = "Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond",

abstract = "Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C-N single bond.",

author = "M. Gandelman and D. Milstein",

year = "2000",

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doi = "10.1039/b004820h",

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T1 - Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

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AU - Milstein, D.

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N2 - Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C-N single bond.

AB - Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C-N single bond.

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JO - Chemical Communications

JF - Chemical Communications

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Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

Abstract

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