Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C-N bond

M. Gandelman, D. Milstein

Research output: Contribution to journalArticlepeer-review

62 Scopus citations

Abstract

Reaction of [RhCl(COE)2]2 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butyl-phosphinomethyl)-2,4,6-trimethylbenze ne (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C-N single bond.

Original languageEnglish
Pages (from-to)1603-1604
Number of pages2
JournalChemical Communications
Issue number17
DOIs
StatePublished - 7 Sep 2000
Externally publishedYes

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