High-yielding and rapid carbon-carbon bond formation from alcohols: Allylation by means of TiCl4

Alfred Hassner; Chennakesava Reddy Bandi

doi:10.1055/s-0033-1338746

High-yielding and rapid carbon-carbon bond formation from alcohols: Allylation by means of TiCl₄

Alfred Hassner
, Chennakesava Reddy Bandi

Department of Chemistry

Bar-Ilan University

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

TiCl₄ efficiently promotes high yield (80-99%) replacement of OH in tertiary, benzylic, and allylic alcohols, and even nonactivated secondary alcohols, by an allyl group. The reaction usually proceeds within minutes at room temperature.

Original language	English
Article number	ST-2013-B0058-L
Pages (from-to)	1275-1279
Number of pages	5
Journal	Synlett
Volume	24
Issue number	10
DOIs	https://doi.org/10.1055/s-0033-1338746
State	Published - 2013

Keywords

C-C bonds
Lewis acid
TiCl
alcohols
allylation
allyltrimethylsilane

Access to Document

10.1055/s-0033-1338746

Cite this

@article{cd174cada6514299a9d1d043c8c2781b,

title = "High-yielding and rapid carbon-carbon bond formation from alcohols: Allylation by means of TiCl4",

abstract = "TiCl4 efficiently promotes high yield (80-99\%) replacement of OH in tertiary, benzylic, and allylic alcohols, and even nonactivated secondary alcohols, by an allyl group. The reaction usually proceeds within minutes at room temperature.",

keywords = "C-C bonds, Lewis acid, TiCl, alcohols, allylation, allyltrimethylsilane",

author = "Alfred Hassner and Bandi, \{Chennakesava Reddy\}",

year = "2013",

doi = "10.1055/s-0033-1338746",

language = "אנגלית",

volume = "24",

pages = "1275--1279",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "10",

}

TY - JOUR

T1 - High-yielding and rapid carbon-carbon bond formation from alcohols

T2 - Allylation by means of TiCl4

AU - Hassner, Alfred

AU - Bandi, Chennakesava Reddy

PY - 2013

Y1 - 2013

N2 - TiCl4 efficiently promotes high yield (80-99%) replacement of OH in tertiary, benzylic, and allylic alcohols, and even nonactivated secondary alcohols, by an allyl group. The reaction usually proceeds within minutes at room temperature.

AB - TiCl4 efficiently promotes high yield (80-99%) replacement of OH in tertiary, benzylic, and allylic alcohols, and even nonactivated secondary alcohols, by an allyl group. The reaction usually proceeds within minutes at room temperature.

KW - C-C bonds

KW - Lewis acid

KW - TiCl

KW - alcohols

KW - allylation

KW - allyltrimethylsilane

UR - https://www.scopus.com/pages/publications/84877609966

U2 - 10.1055/s-0033-1338746

DO - 10.1055/s-0033-1338746

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84877609966

SN - 0936-5214

VL - 24

SP - 1275

EP - 1279

JO - Synlett

JF - Synlett

IS - 10

M1 - ST-2013-B0058-L

ER -

High-yielding and rapid carbon-carbon bond formation from alcohols: Allylation by means of TiCl₄

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this