TY - JOUR
T1 - High-yielding and rapid carbon-carbon bond formation from alcohols
T2 - Allylation by means of TiCl4
AU - Hassner, Alfred
AU - Bandi, Chennakesava Reddy
PY - 2013
Y1 - 2013
N2 - TiCl4 efficiently promotes high yield (80-99%) replacement of OH in tertiary, benzylic, and allylic alcohols, and even nonactivated secondary alcohols, by an allyl group. The reaction usually proceeds within minutes at room temperature.
AB - TiCl4 efficiently promotes high yield (80-99%) replacement of OH in tertiary, benzylic, and allylic alcohols, and even nonactivated secondary alcohols, by an allyl group. The reaction usually proceeds within minutes at room temperature.
KW - C-C bonds
KW - Lewis acid
KW - TiCl
KW - alcohols
KW - allylation
KW - allyltrimethylsilane
UR - http://www.scopus.com/inward/record.url?scp=84877609966&partnerID=8YFLogxK
U2 - 10.1055/s-0033-1338746
DO - 10.1055/s-0033-1338746
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AN - SCOPUS:84877609966
SN - 0936-5214
VL - 24
SP - 1275
EP - 1279
JO - Synlett
JF - Synlett
IS - 10
M1 - ST-2013-B0058-L
ER -