Helical Anthracene-Ethyne-Based MOF-74 Analogue

Patricia I. Scheurle; Andre Mähringer; Tabea Haug; Alexander Biewald; Daniel Axthammer; Achim Hartschuh; Lena Harms; Gunther Wittstock; Dana D. Medina; Thomas Bein

doi:10.1021/acs.cgd.1c01145

Helical Anthracene-Ethyne-Based MOF-74 Analogue

Patricia I. Scheurle
, Andre Mähringer
, Tabea Haug
, Alexander Biewald
, Daniel Axthammer
, Achim Hartschuh
, Lena Harms
, Gunther Wittstock
, Dana D. Medina
, Thomas Bein

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A flexible, electron-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topology. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photoluminescence.

Original language	English
Pages (from-to)	2849-2853
Number of pages	5
Journal	Crystal Growth and Design
Volume	22
Issue number	5
DOIs	https://doi.org/10.1021/acs.cgd.1c01145
State	Published - 4 May 2022
Externally published	Yes

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© 2022 The Authors.

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10.1021/acs.cgd.1c01145

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title = "Helical Anthracene-Ethyne-Based MOF-74 Analogue",

abstract = "A flexible, electron-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topology. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photoluminescence.",

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doi = "10.1021/acs.cgd.1c01145",

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AU - Scheurle, Patricia I.

AU - Mähringer, Andre

AU - Haug, Tabea

AU - Biewald, Alexander

AU - Axthammer, Daniel

AU - Hartschuh, Achim

AU - Harms, Lena

AU - Wittstock, Gunther

AU - Medina, Dana D.

AU - Bein, Thomas

PY - 2022/5/4

Y1 - 2022/5/4

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AB - A flexible, electron-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topology. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photoluminescence.

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 5

ER -

Helical Anthracene-Ethyne-Based MOF-74 Analogue

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