Helical Anthracene-Ethyne-Based MOF-74 Analogue

Patricia I. Scheurle, Andre Mähringer, Tabea Haug, Alexander Biewald, Daniel Axthammer, Achim Hartschuh, Lena Harms, Gunther Wittstock, Dana D. Medina, Thomas Bein

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A flexible, electron-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topology. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photoluminescence.

Original languageEnglish
Pages (from-to)2849-2853
Number of pages5
JournalCrystal Growth and Design
Volume22
Issue number5
DOIs
StatePublished - 4 May 2022
Externally publishedYes

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