Graphene oxide grafted with iridium complex as a superior heterogeneous catalyst for chemical fixation of carbon dioxide to dimethylformamide

Subodh Kumar; Pawan Kumar; Arghya Deb; Debabrata Maiti; Suman L. Jain

doi:10.1016/j.carbon.2016.01.018

Graphene oxide grafted with iridium complex as a superior heterogeneous catalyst for chemical fixation of carbon dioxide to dimethylformamide

Subodh Kumar, Pawan Kumar, Arghya Deb, Debabrata Maiti, Suman L. Jain

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31 Scopus citations

Abstract

A novel graphene oxide (GO)-immobilized heteroleptic iridium complex was synthesized and demonstrated as a first heterogenized homogeneous catalyst for the production of dimethylformamide (DMF) from carbon dioxide, hydrogen, and dimethylamine. The synthesized hybrid catalyst showed comparable activity as homogeneous heteroleptic iridium complex with additional benefits such as facile recovery and recycling of the catalyst. After completion of the reaction, the heterogeneous catalyst was easily recovered by filtration, and reused for subsequent recycling processes without any significant change in the catalytic efficiency.

Original language	English
Pages (from-to)	632-640
Number of pages	9
Journal	Carbon
Volume	100
DOIs	https://doi.org/10.1016/j.carbon.2016.01.018
State	Published - 1 Apr 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 Elsevier Ltd. All rights reserved.

Funding

We are thankful to the director of CSIR-Indian Institute of Petroleum, for granting permission to publish the results. Pawan Kumar and Subodh Kumar acknowledge CSIR, New Delhi, for providing research fellowships. Department of Science and Technology (DST) ( GAP 3122 ), New Delhi, is kindly acknowledged for funding.

Funders	Funder number
Department of Science and Technology	GAP 3122
Council of Scientific and Industrial Research, India

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abstract = "A novel graphene oxide (GO)-immobilized heteroleptic iridium complex was synthesized and demonstrated as a first heterogenized homogeneous catalyst for the production of dimethylformamide (DMF) from carbon dioxide, hydrogen, and dimethylamine. The synthesized hybrid catalyst showed comparable activity as homogeneous heteroleptic iridium complex with additional benefits such as facile recovery and recycling of the catalyst. After completion of the reaction, the heterogeneous catalyst was easily recovered by filtration, and reused for subsequent recycling processes without any significant change in the catalytic efficiency.",

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AU - Kumar, Pawan

AU - Deb, Arghya

AU - Maiti, Debabrata

AU - Jain, Suman L.

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AB - A novel graphene oxide (GO)-immobilized heteroleptic iridium complex was synthesized and demonstrated as a first heterogenized homogeneous catalyst for the production of dimethylformamide (DMF) from carbon dioxide, hydrogen, and dimethylamine. The synthesized hybrid catalyst showed comparable activity as homogeneous heteroleptic iridium complex with additional benefits such as facile recovery and recycling of the catalyst. After completion of the reaction, the heterogeneous catalyst was easily recovered by filtration, and reused for subsequent recycling processes without any significant change in the catalytic efficiency.

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Graphene oxide grafted with iridium complex as a superior heterogeneous catalyst for chemical fixation of carbon dioxide to dimethylformamide

Abstract

Bibliographical note

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