Functionalized Chitosan-Carbon Dots: A Fluorescent Probe for Detecting Trace Amount of Water in Organic Solvents

Shweta Pawar, Uday Kumar Togiti, Anupam Bhattacharya, Amit Nag

Research output: Contribution to journalArticlepeer-review

72 Scopus citations

Abstract

A novel nanoprobe was designed and synthesized by functionalizing chitosan-carbon dots (CDs) with a modified bipyridine-based heterocyclic molecule, 4-(pyridine-2-yl)-3H-pyrrolo[2,3-c]quinoline (PPQ), to detect trace amount of water via fluorescence methods. The functionalized CDs (PPQ-CDs) were thoroughly characterized using dynamic light scattering, UV-vis, X-ray diffraction, Fourier transform infrared, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, and NMR techniques. The modified fluorescence intensity of PPQ-CDs was found to be an excellent indicator for water in organic solvents. The PPQ-CDs showed very weak fluorescence intensity in organic solvents due to a possible photoinduced electron transfer (PET) process between PPQ pyrrole nitrogen and acceptor groups of CDs. However, sequential addition of trace amount of water led to continuous enhancement in the fluorescence intensity for the PPQ-CD nanocomposites. The mechanism was proposed to follow suppression of the PET process due to the formation of "free-ions" by the proton transfer from the CD carboxyl group to pyrrole nitrogen through water bridging. The limit of water detection was determined to be 0.023% (v/v) in DMSO.

Original languageEnglish
Pages (from-to)11301-11311
Number of pages11
JournalACS Omega
Volume4
Issue number6
DOIs
StatePublished - 30 Jun 2019
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2019 American Chemical Society.

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