Functionalization of WS                         2                          Nanotubes with Fluorescent C-dots and Conductive Polythiophenes

Vijay Bhooshan Kumar; Yifat Harel; Rivka Ben-Ishay; Jean Paul Lellouche; Aharon Gedanken

doi:10.1002/macp.201800476

Functionalization of WS ₂ Nanotubes with Fluorescent C-dots and Conductive Polythiophenes

Vijay Bhooshan Kumar, Yifat Harel, Rivka Ben-Ishay, Jean Paul Lellouche, Aharon Gedanken

Department of Chemistry

Bar-Ilan University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Multifunctional nanoparticles have attracted significant interest for their multifunctional applications. Described herein is the building of a new hybrid nanocomposite particle, conjugating tungsten disulfide (WS ₂ ) nanotubes (NTs) to fluorescent carbon dots (C-dots). Hybrid WS ₂ -C-dots hyb-NTs nanomaterials are prepared by a hydrothermal reaction of PEDOT _Ac -WS ₂ NTs, where the PEDOT _Ac (poly 2,3-dihydrothieno[3,4-b][1,4]dioxine-2-carboxylic acid) polymer serves as the C-dots precursor. The physical and chemical properties of the as-synthesized WS ₂ -C-dots hyb-NTs are determined by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), CHNSO analysis, and fluorescence, Raman, and UV–vis absorption spectroscopy. The WS ₂ -C-dots hyb-NTs are shown to be very stable at normal room temperature and pressure and could be useful for multicolor cell imaging and targeted cell killing.

Original language	English
Article number	1800476
Journal	Macromolecular Chemistry and Physics
Volume	220
Issue number	7
DOIs	https://doi.org/10.1002/macp.201800476
State	Published - Apr 2019

Bibliographical note

Publisher Copyright:
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

The authors thank Ortal Lidor-Shalev of the Department of Chemistry at Bar-Ilan University for her help with TEM and HRSEM measurements, and gratefully acknowledge the Israel National Nanotechnology Initiative Focal Technology Area (FTA) project “Inorganic nanotubes: from nanomechanics to improved nano-composites” and Prof. Reshef Tenne of the Weizmann Institute, the FTA program coordinator, for partial funding of this research. The authors thank Ortal Lidor-Shalev of the Department of Chemistry at Bar-Ilan University for her help with TEM and HRSEM measurements, and gratefully acknowledge the Israel National Nanotechnology Initiative Focal Technology Area (FTA) project ?Inorganic nanotubes: from nanomechanics to improved nano-composites? and Prof. Reshef Tenne of the Weizmann Institute, the FTA program coordinator, for partial funding of this research.

Funders	Funder number
Israel National Nanotechnology Initiative Focal Technology Area
Weizmann Institute
Federal Transit Administration
Weizmann Institute of Science

Keywords

C-dots
NTs functionalization
WS -C-dots hybrid-NTs
WS NTs

Access to Document

10.1002/macp.201800476

Cite this

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title = " Functionalization of WS 2 Nanotubes with Fluorescent C-dots and Conductive Polythiophenes ",

abstract = " Multifunctional nanoparticles have attracted significant interest for their multifunctional applications. Described herein is the building of a new hybrid nanocomposite particle, conjugating tungsten disulfide (WS 2 ) nanotubes (NTs) to fluorescent carbon dots (C-dots). Hybrid WS 2 -C-dots hyb-NTs nanomaterials are prepared by a hydrothermal reaction of PEDOT Ac -WS 2 NTs, where the PEDOT Ac (poly 2,3-dihydrothieno[3,4-b][1,4]dioxine-2-carboxylic acid) polymer serves as the C-dots precursor. The physical and chemical properties of the as-synthesized WS 2 -C-dots hyb-NTs are determined by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), CHNSO analysis, and fluorescence, Raman, and UV–vis absorption spectroscopy. The WS 2 -C-dots hyb-NTs are shown to be very stable at normal room temperature and pressure and could be useful for multicolor cell imaging and targeted cell killing.",

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Functionalization of WS ₂ Nanotubes with Fluorescent C-dots and Conductive Polythiophenes . / Kumar, Vijay Bhooshan; Harel, Yifat; Ben-Ishay, Rivka et al.
In: Macromolecular Chemistry and Physics, Vol. 220, No. 7, 1800476, 04.2019.

Research output: Contribution to journal › Article › peer-review

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