Fractional dynamics approach to diffusion-assisted reactions in disordered media

Jaeyoung Sung, Eli Barkai, Robert J. Silbey, Sangyoub Lee

Research output: Contribution to journalArticlepeer-review

68 Scopus citations

Abstract

A theory for describing nonclassical dynamics of reactions occurring in disordered media was presented based on the fractional diffusion equation. An expression for the Green's function was derived which was required to calculate the survival probabilities of reactants. A novel kinetic phase transition dependent on temperature was found. The theory explained the observed features of ligand-protein recombination reactions in a unified manner for a wide range of temperature and time scales.

Original languageEnglish
Pages (from-to)2338-2341
Number of pages4
JournalJournal of Chemical Physics
Volume116
Issue number6
DOIs
StatePublished - 8 Feb 2002
Externally publishedYes

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