Flower-like porous cobalt(II) monoxide nanostructures as anode material for Li-ion batteries

Anirudha Jena, Tirupathi Rao Penki, N. Munichandraiah, S. A. Shivashankar

Research output: Contribution to journalArticlepeer-review

33 Scopus citations

Abstract

In the present study, a microwave-assisted, solution-based route has been employed to obtain porous CoO nanostructures. Detailed characterization reveals that the flower-like nanostructures comprise petal-like sheets, each of which is made of an ordered, porous arrangement of crystallites of CoO measuring about 6 nm. TEM analysis shows that each "petal" is an oriented aggregate of CoO nanocrystals, such aggregation promoted by the hydroxyl moieties derived from the solution. The structure provides a large specific area as well as the porosity desirable in electrodes in Li-ion batteries. Electrochemical measurements carried out on electrodes made of nanostructured CoO show excellent Li ion-storing capability. A specific capacitance of 779 mAh g-1 has been measured at a specific current of 100 mA g-1. Measurements show also excellent cyclability and coulombic efficiency. Impedance spectroscopy provides evidence for charge transfer occurring in the porous networks.

Original languageEnglish
Pages (from-to)21-27
Number of pages7
JournalJournal of Electroanalytical Chemistry
Volume761
DOIs
StatePublished - 15 Jan 2016
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.

Keywords

  • Cobalt monoxide
  • Lithium ion battery
  • Metalorganic complex
  • Microwave

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