Abstract
Optically active Lewis acids and Lewis pairs were synthesized and characterized by multinuclear NMR, UV/Vis spectroscopy and elemental analysis. Optical rotation measurements were carried out and the absolute configuration of the new chiral molecules confirmed by single crystal X-ray diffraction.
| Original language | English |
|---|---|
| Pages (from-to) | 41-49 |
| Number of pages | 9 |
| Journal | Journal of Chemical Sciences |
| Volume | 125 |
| Issue number | 1 |
| DOIs | |
| State | Published - Jan 2013 |
| Externally published | Yes |
Bibliographical note
Funding Information:This work was supported by the Department of Science and Technology (DST), New Delhi, India and Indian Institute of Science (IISc), Bangalore. PS thanks IISc, Bangalore for research fellowship.
Funding
This work was supported by the Department of Science and Technology (DST), New Delhi, India and Indian Institute of Science (IISc), Bangalore. PS thanks IISc, Bangalore for research fellowship.
| Funders |
|---|
| Indian Institute of Science |
| Department of Science and Technology, Ministry of Science and Technology, India |
Keywords
- Ferrocene/Lewis acid
- frustrated Lewis pairs
- optical rotation
- organoborane
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