Ferrocene-based Lewis acids and Lewis pairs: Synthesis and structural characterization

Pagidi Sudhakar; Pakkirisamy Thilagar

doi:10.1007/s12039-012-0356-8

Ferrocene-based Lewis acids and Lewis pairs: Synthesis and structural characterization

Pagidi Sudhakar, Pakkirisamy Thilagar

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Optically active Lewis acids and Lewis pairs were synthesized and characterized by multinuclear NMR, UV/Vis spectroscopy and elemental analysis. Optical rotation measurements were carried out and the absolute configuration of the new chiral molecules confirmed by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	41-49
Number of pages	9
Journal	Journal of Chemical Sciences
Volume	125
Issue number	1
DOIs	https://doi.org/10.1007/s12039-012-0356-8
State	Published - Jan 2013
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported by the Department of Science and Technology (DST), New Delhi, India and Indian Institute of Science (IISc), Bangalore. PS thanks IISc, Bangalore for research fellowship.

Keywords

Ferrocene/Lewis acid
frustrated Lewis pairs
optical rotation
organoborane

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abstract = "Optically active Lewis acids and Lewis pairs were synthesized and characterized by multinuclear NMR, UV/Vis spectroscopy and elemental analysis. Optical rotation measurements were carried out and the absolute configuration of the new chiral molecules confirmed by single crystal X-ray diffraction.",

keywords = "Ferrocene/Lewis acid, frustrated Lewis pairs, optical rotation, organoborane",

author = "Pagidi Sudhakar and Pakkirisamy Thilagar",

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KW - frustrated Lewis pairs

KW - optical rotation

KW - organoborane

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Ferrocene-based Lewis acids and Lewis pairs: Synthesis and structural characterization

Abstract

Bibliographical note

Keywords

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