Electrophilic formamidines. Organometallic addition to 2-methoxy pyrrolidine or piperidine N-t-butyl formamidines. Formation of 2-substituted pyrrolidines and piperidines.

Levi Gottlieb; A. I. Meyers

doi:10.1016/s0040-4039(00)97716-5

Electrophilic formamidines. Organometallic addition to 2-methoxy pyrrolidine or piperidine N-t-butyl formamidines. Formation of 2-substituted pyrrolidines and piperidines.

Levi Gottlieb, A. I. Meyers

Colorado State University

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Abstract

The title compounds were prepared by addition of Grignard reagents to methoxyformamidines 6 and 8 in ether at room temperature. Hydrolysis gives the free secondary amines, or in cases of volatile products, their thiourea derivatives.

Original language	English
Pages (from-to)	4723-4726
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	33
DOIs	https://doi.org/10.1016/s0040-4039(00)97716-5
State	Published - 1990
Externally published	Yes

Bibliographical note

Funding Information:
Financial support from the National Science Foundation is gratefullya cknowledged.

Funding

Financial support from the National Science Foundation is gratefullya cknowledged.

Funders	Funder number
National Science Foundation

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10.1016/s0040-4039(00)97716-5

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title = "Electrophilic formamidines. Organometallic addition to 2-methoxy pyrrolidine or piperidine N-t-butyl formamidines. Formation of 2-substituted pyrrolidines and piperidines.",

abstract = "The title compounds were prepared by addition of Grignard reagents to methoxyformamidines 6 and 8 in ether at room temperature. Hydrolysis gives the free secondary amines, or in cases of volatile products, their thiourea derivatives.",

author = "Levi Gottlieb and Meyers, {A. I.}",

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AU - Gottlieb, Levi

AU - Meyers, A. I.

N1 - Funding Information: Financial support from the National Science Foundation is gratefullya cknowledged.

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Y1 - 1990

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Electrophilic formamidines. Organometallic addition to 2-methoxy pyrrolidine or piperidine N-t-butyl formamidines. Formation of 2-substituted pyrrolidines and piperidines.

Abstract

Bibliographical note

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