Electron-conducting polymers: Electrochemical doping and equilibrium potential distribution across metal-polymer-solution interfaces

M. D. Levi; M. A. Vorotyntsev; V. E. Kazarinov; A. N. Frumkin

doi:10.1016/0379-6779(91)91207-q

Electron-conducting polymers: Electrochemical doping and equilibrium potential distribution across metal-polymer-solution interfaces

M. D. Levi
, M. A. Vorotyntsev
, V. E. Kazarinov
, A. N. Frumkin

Russian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A thermodynamic analysis of the potential distribution in an equilibrium galvanic curcuit with a conducting polymer film electrode permeable for anions has been carried out. The distribution of the total potential difference between two interfaces (metal-polymer and polymer-electrolyte solution) and, hence, the dependence of concentrations of all charged redox forms on the potential E are determined by the type of charged form that prevails in the polymer film (of polaron or bipolaron type, in particular).

Original language	English
Pages (from-to)	2923-2925
Number of pages	3
Journal	Synthetic Metals
Volume	43
Issue number	1-2
DOIs	https://doi.org/10.1016/0379-6779(91)91207-q
State	Published - 7 Jun 1991
Externally published	Yes

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abstract = "A thermodynamic analysis of the potential distribution in an equilibrium galvanic curcuit with a conducting polymer film electrode permeable for anions has been carried out. The distribution of the total potential difference between two interfaces (metal-polymer and polymer-electrolyte solution) and, hence, the dependence of concentrations of all charged redox forms on the potential E are determined by the type of charged form that prevails in the polymer film (of polaron or bipolaron type, in particular).",

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AU - Frumkin, A. N.

PY - 1991/6/7

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AB - A thermodynamic analysis of the potential distribution in an equilibrium galvanic curcuit with a conducting polymer film electrode permeable for anions has been carried out. The distribution of the total potential difference between two interfaces (metal-polymer and polymer-electrolyte solution) and, hence, the dependence of concentrations of all charged redox forms on the potential E are determined by the type of charged form that prevails in the polymer film (of polaron or bipolaron type, in particular).

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Electron-conducting polymers: Electrochemical doping and equilibrium potential distribution across metal-polymer-solution interfaces

Abstract

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