TY - JOUR
T1 - ELECTROINITIATED OLIGOMERIZATION OF METHYL ACRYLATE IN METHANOL SOLUTION.
AU - Albeck, Michael
AU - Karoly, Aharon
PY - 1975
Y1 - 1975
N2 - In the reported investigation, the electroinitiated oligomerization of methyl acrylate in methanol solution in the presence of lithium acetate was studied. It was found that in this system the initiator is the methyl radical (obtained from anodic oxidation of acetate ion), and the major termination step is the abstraction of hydrogen radical from methanol by the growing oligomer chain. Eleven compounds were found to be formed in the reaction. A reaction sequence for their formation together with an electric balance for the reactions is given.
AB - In the reported investigation, the electroinitiated oligomerization of methyl acrylate in methanol solution in the presence of lithium acetate was studied. It was found that in this system the initiator is the methyl radical (obtained from anodic oxidation of acetate ion), and the major termination step is the abstraction of hydrogen radical from methanol by the growing oligomer chain. Eleven compounds were found to be formed in the reaction. A reaction sequence for their formation together with an electric balance for the reactions is given.
UR - http://www.scopus.com/inward/record.url?scp=0016647881&partnerID=8YFLogxK
U2 - 10.1002/pol.1975.170131205
DO - 10.1002/pol.1975.170131205
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AN - SCOPUS:0016647881
SN - 0449-296X
VL - 13
SP - 2699
EP - 2707
JO - Journal of polymer science. Part A-1, Polymer chemistry
JF - Journal of polymer science. Part A-1, Polymer chemistry
IS - 12
ER -