Electrochemical quartz crystal microbalance (EQCM) studies of ions and solvents insertion into highly porous activated carbons

Mikhael D. Levi; Naomi Levy; Sergey Sigalov; Gregory Salitra; Doron Aurbach; Joachim Maier

doi:10.1021/ja104391g

Electrochemical quartz crystal microbalance (EQCM) studies of ions and solvents insertion into highly porous activated carbons

Mikhael D. Levi
, Naomi Levy
, Sergey Sigalov
, Gregory Salitra
, Doron Aurbach
, Joachim Maier

Department of Chemistry

Max Planck Institute for Solid State Research

Research output: Contribution to journal › Article › peer-review

165 Scopus citations

Abstract

Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in micropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li ⁺ cations when adsorbed in carbon micropores.

Original language	English
Pages (from-to)	13220-13222
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	38
DOIs	https://doi.org/10.1021/ja104391g
State	Published - 29 Sep 2010

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10.1021/ja104391g

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abstract = "Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in micropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li + cations when adsorbed in carbon micropores.",

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AU - Levi, Mikhael D.

AU - Levy, Naomi

AU - Sigalov, Sergey

AU - Salitra, Gregory

AU - Aurbach, Doron

AU - Maier, Joachim

PY - 2010/9/29

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N2 - Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in micropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li + cations when adsorbed in carbon micropores.

AB - Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in micropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li + cations when adsorbed in carbon micropores.

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Electrochemical quartz crystal microbalance (EQCM) studies of ions and solvents insertion into highly porous activated carbons

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