Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode

Subramanian Ramanathan; Elaiyappillai Elanthamilan; Asir Obadiah; Arulappan Durairaj; Palanisamy Santhoshkumar; Johnson Princy Merlin; Subramanian Ramasundaram; Samuel Vasanthkumar

doi:10.1007/s11664-019-07233-3

Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode

Subramanian Ramanathan, Elaiyappillai Elanthamilan, Asir Obadiah, Arulappan Durairaj, Palanisamy Santhoshkumar, Johnson Princy Merlin, Subramanian Ramasundaram, Samuel Vasanthkumar

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

This paper reports the electrochemical sensing of trace amounts of arsenic (As (III)) in broiler meat using a graphene oxide-bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)cobalt composite (GO-Co (DIP)) composite modified electrode. The synthesized nanocomposite was characterized by Fourier transform infrared spectrometry, x-ray diffraction and scanning electron microscopy techniques. The electrochemical studies were carried out by cyclic and pulse voltammetry techniques. To detect the trace amount of As (III) with a highest sensing ability, optimization of some of the analytical factors such as pH, scan rate, deposition time, concentration, pulse height and pulse width were carried out. Employing optimized conditions, the oxidation peak current of As (III) was obtained in the range from − 1.0 V to 1.0 V and it exhibited a very low detection limit of 0.04 μM. The developed GO-Co (DIP) composite modified electrode was used to detect the trace amount of As (III) in broiler meat and a comparison was also carried out with the meat of native breeds.

Original language	English
Pages (from-to)	4498-4506
Number of pages	9
Journal	Journal of Electronic Materials
Volume	48
Issue number	7
DOIs	https://doi.org/10.1007/s11664-019-07233-3
State	Published - 15 Jul 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019, The Minerals, Metals & Materials Society.

Funding

The authors thank the Management and Administration of Karunya University for their support and help. The authors are grateful to Department of Science and Technology, Govt. of India for their financial support.

Funders	Funder number
Department of Science and Technology, Government of Kerala

Keywords

GO-Co (DIP) composite
bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)cobalt (DIP)
broiler meat
electrochemical
voltammetry

Access to Document

10.1007/s11664-019-07233-3

Cite this

Ramanathan, S., Elanthamilan, E., Obadiah, A., Durairaj, A., Santhoshkumar, P., Merlin, J. P., Ramasundaram, S., & Vasanthkumar, S. (2019). Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode. Journal of Electronic Materials, 48(7), 4498-4506. https://doi.org/10.1007/s11664-019-07233-3

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title = "Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode",

abstract = "This paper reports the electrochemical sensing of trace amounts of arsenic (As (III)) in broiler meat using a graphene oxide-bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)cobalt composite (GO-Co (DIP)) composite modified electrode. The synthesized nanocomposite was characterized by Fourier transform infrared spectrometry, x-ray diffraction and scanning electron microscopy techniques. The electrochemical studies were carried out by cyclic and pulse voltammetry techniques. To detect the trace amount of As (III) with a highest sensing ability, optimization of some of the analytical factors such as pH, scan rate, deposition time, concentration, pulse height and pulse width were carried out. Employing optimized conditions, the oxidation peak current of As (III) was obtained in the range from − 1.0 V to 1.0 V and it exhibited a very low detection limit of 0.04 μM. The developed GO-Co (DIP) composite modified electrode was used to detect the trace amount of As (III) in broiler meat and a comparison was also carried out with the meat of native breeds.",

keywords = "GO-Co (DIP) composite, bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)cobalt (DIP), broiler meat, electrochemical, voltammetry",

author = "Subramanian Ramanathan and Elaiyappillai Elanthamilan and Asir Obadiah and Arulappan Durairaj and Palanisamy Santhoshkumar and Merlin, {Johnson Princy} and Subramanian Ramasundaram and Samuel Vasanthkumar",

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Ramanathan, S, Elanthamilan, E, Obadiah, A, Durairaj, A, Santhoshkumar, P, Merlin, JP, Ramasundaram, S & Vasanthkumar, S 2019, 'Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode', Journal of Electronic Materials, vol. 48, no. 7, pp. 4498-4506. https://doi.org/10.1007/s11664-019-07233-3

Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode. / Ramanathan, Subramanian; Elanthamilan, Elaiyappillai; Obadiah, Asir et al.
In: Journal of Electronic Materials, Vol. 48, No. 7, 15.07.2019, p. 4498-4506.

Research output: Contribution to journal › Article › peer-review

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T1 - Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode

AU - Ramanathan, Subramanian

AU - Elanthamilan, Elaiyappillai

AU - Obadiah, Asir

AU - Durairaj, Arulappan

AU - Santhoshkumar, Palanisamy

AU - Merlin, Johnson Princy

AU - Ramasundaram, Subramanian

AU - Vasanthkumar, Samuel

PY - 2019/7/15

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AB - This paper reports the electrochemical sensing of trace amounts of arsenic (As (III)) in broiler meat using a graphene oxide-bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)cobalt composite (GO-Co (DIP)) composite modified electrode. The synthesized nanocomposite was characterized by Fourier transform infrared spectrometry, x-ray diffraction and scanning electron microscopy techniques. The electrochemical studies were carried out by cyclic and pulse voltammetry techniques. To detect the trace amount of As (III) with a highest sensing ability, optimization of some of the analytical factors such as pH, scan rate, deposition time, concentration, pulse height and pulse width were carried out. Employing optimized conditions, the oxidation peak current of As (III) was obtained in the range from − 1.0 V to 1.0 V and it exhibited a very low detection limit of 0.04 μM. The developed GO-Co (DIP) composite modified electrode was used to detect the trace amount of As (III) in broiler meat and a comparison was also carried out with the meat of native breeds.

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Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode

Abstract

Bibliographical note

Funding

Keywords

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