TY - JOUR
T1 - Electrochemical decomposition of biformylperoxide. A quantum mechanical calculation
AU - Albeck, Michael
AU - Shaik, Sason
PY - 1978
Y1 - 1978
N2 - Quantum mechanical calculations were performed on the primary products of electrodic redox reactions of biformylperoxide. The calculations predicted that CO2, O2, H2, (chemical equation presented), H2CO and HCOOH should be the final products of the reaction. Experiments on benzoylperoxide showed the presence of O2, (chemical equation presented) and (chemical equation presented) beside CO2, φφ and (chemical equation presented) which are also the thermal decomposition products of benzoylperoxide.
AB - Quantum mechanical calculations were performed on the primary products of electrodic redox reactions of biformylperoxide. The calculations predicted that CO2, O2, H2, (chemical equation presented), H2CO and HCOOH should be the final products of the reaction. Experiments on benzoylperoxide showed the presence of O2, (chemical equation presented) and (chemical equation presented) beside CO2, φφ and (chemical equation presented) which are also the thermal decomposition products of benzoylperoxide.
UR - http://www.scopus.com/inward/record.url?scp=37049095669&partnerID=8YFLogxK
U2 - 10.1039/F19787401496
DO - 10.1039/F19787401496
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AN - SCOPUS:37049095669
SN - 0300-9599
VL - 74
SP - 1496
EP - 1499
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
ER -