Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion

M. D. Levi; E. Yu Pisarevskaya; E. B. Molodkina; A. I. Danilov

doi:10.1016/0379-6779(93)91060-f

Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion

M. D. Levi, E. Yu Pisarevskaya, E. B. Molodkina, A. I. Danilov

Russian Academy of Sciences

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8 Scopus citations

Abstract

Poly(p-phenylene) (PPP) films deposited from benzene in concentrated H₂SO₄ emulsion reveal a highly crystalline structure under TEM, SEM and XDA in contrast to nearly completely amorphous films deposited from C₆H₅NO₂ medium. Possible effects of solvent and electrolyte specificity on the morphology and mechanical properties of PPP films are discussed in view of these results.

Original language	English
Pages (from-to)	195-201
Number of pages	7
Journal	Synthetic Metals
Volume	54
Issue number	1-3
DOIs	https://doi.org/10.1016/0379-6779(93)91060-f
State	Published - 1 Mar 1993
Externally published	Yes

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title = "Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion",

abstract = "Poly(p-phenylene) (PPP) films deposited from benzene in concentrated H2SO4 emulsion reveal a highly crystalline structure under TEM, SEM and XDA in contrast to nearly completely amorphous films deposited from C6H5NO2 medium. Possible effects of solvent and electrolyte specificity on the morphology and mechanical properties of PPP films are discussed in view of these results.",

author = "Levi, {M. D.} and Pisarevskaya, {E. Yu} and Molodkina, {E. B.} and Danilov, {A. I.}",

year = "1993",

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doi = "10.1016/0379-6779(93)91060-f",

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Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion. / Levi, M. D.; Pisarevskaya, E. Yu; Molodkina, E. B. et al.
In: Synthetic Metals, Vol. 54, No. 1-3, 01.03.1993, p. 195-201.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion

AU - Levi, M. D.

AU - Pisarevskaya, E. Yu

AU - Molodkina, E. B.

AU - Danilov, A. I.

PY - 1993/3/1

Y1 - 1993/3/1

N2 - Poly(p-phenylene) (PPP) films deposited from benzene in concentrated H2SO4 emulsion reveal a highly crystalline structure under TEM, SEM and XDA in contrast to nearly completely amorphous films deposited from C6H5NO2 medium. Possible effects of solvent and electrolyte specificity on the morphology and mechanical properties of PPP films are discussed in view of these results.

AB - Poly(p-phenylene) (PPP) films deposited from benzene in concentrated H2SO4 emulsion reveal a highly crystalline structure under TEM, SEM and XDA in contrast to nearly completely amorphous films deposited from C6H5NO2 medium. Possible effects of solvent and electrolyte specificity on the morphology and mechanical properties of PPP films are discussed in view of these results.

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Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion

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