TY - JOUR
T1 - Effect of solvents on the electrochemistry of olefins and aromatic molecules
AU - Margel, Shlomo
AU - Levy, Moshe
PY - 1977/8/25
Y1 - 1977/8/25
N2 - Cyclic voltammetry and electrolysis studies were carried out in dimethyl sulfoxide, diglyme and liquid ammonia. The depolarizers were diethyl fumarate, ethyl cinnamate, stilbene and anthracene. The reduction reactions were carried out in the presence of organic halides, phenol, acids and water. The rates of the reactions were measured. The main solvent effect was noticed with water which reacts 100 times faster in diglyme than in liquid ammonia or DMSO. The results of electrolytic experiments with two reactants simultaneously were compared with those predicted from the kinetic data.
AB - Cyclic voltammetry and electrolysis studies were carried out in dimethyl sulfoxide, diglyme and liquid ammonia. The depolarizers were diethyl fumarate, ethyl cinnamate, stilbene and anthracene. The reduction reactions were carried out in the presence of organic halides, phenol, acids and water. The rates of the reactions were measured. The main solvent effect was noticed with water which reacts 100 times faster in diglyme than in liquid ammonia or DMSO. The results of electrolytic experiments with two reactants simultaneously were compared with those predicted from the kinetic data.
UR - http://www.scopus.com/inward/record.url?scp=49449123835&partnerID=8YFLogxK
U2 - 10.1016/S0022-0728(77)80032-6
DO - 10.1016/S0022-0728(77)80032-6
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AN - SCOPUS:49449123835
SN - 0022-0728
VL - 81
SP - 357
EP - 364
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
IS - 2
ER -