Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

Dan Meyerstein; Israel Zilbermann; Haim Cohen; Rudi Van Eldik

doi:10.1080/08957959108203213

Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

Dan Meyerstein
, Israel Zilbermann
, Haim Cohen
, Rudi Van Eldik

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.

Original language	English
Pages (from-to)	287-290
Number of pages	4
Journal	High Pressure Research
Volume	6
Issue number	5
DOIs	https://doi.org/10.1080/08957959108203213
State	Published - Dec 1991
Externally published	Yes

Bibliographical note

Funding Information:
The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.

Funding

The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.

Funders
Deutsche Forschungsgemeinschaft
Volkswagen Foundation
German-Israeli Foundation for Scientific Research and Development

Keywords

aqueous phase chemistry
electron-transfer
high-pressure pulse-radiolysis
reaction kinetics

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10.1080/08957959108203213

Cite this

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title = "Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis",

abstract = "The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.",

keywords = "aqueous phase chemistry, electron-transfer, high-pressure pulse-radiolysis, reaction kinetics",

author = "Dan Meyerstein and Israel Zilbermann and Haim Cohen and Eldik, \{Rudi Van\}",

note = "Funding Information: The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.",

year = "1991",

month = dec,

doi = "10.1080/08957959108203213",

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AU - Meyerstein, Dan

AU - Zilbermann, Israel

AU - Cohen, Haim

AU - Eldik, Rudi Van

N1 - Funding Information: The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.

PY - 1991/12

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N2 - The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.

AB - The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.

KW - aqueous phase chemistry

KW - electron-transfer

KW - high-pressure pulse-radiolysis

KW - reaction kinetics

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ER -

Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

Abstract

Bibliographical note

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Keywords

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