Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

Dan Meyerstein; Israel Zilbermann; Haim Cohen; Rudi Van Eldik

doi:10.1080/08957959108203213

Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

Dan Meyerstein, Israel Zilbermann, Haim Cohen, Rudi Van Eldik

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.

Original language	English
Pages (from-to)	287-290
Number of pages	4
Journal	High Pressure Research
Volume	6
Issue number	5
DOIs	https://doi.org/10.1080/08957959108203213
State	Published - Dec 1991
Externally published	Yes

Bibliographical note

Funding Information:
The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.

Keywords

aqueous phase chemistry
electron-transfer
high-pressure pulse-radiolysis
reaction kinetics

Access to Document

10.1080/08957959108203213

Cite this

@article{81f5554685154c7bb6336e808185d518,

title = "Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis",

abstract = "The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.",

keywords = "aqueous phase chemistry, electron-transfer, high-pressure pulse-radiolysis, reaction kinetics",

author = "Dan Meyerstein and Israel Zilbermann and Haim Cohen and Eldik, {Rudi Van}",

note = "Funding Information: The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.",

year = "1991",

month = dec,

doi = "10.1080/08957959108203213",

language = "אנגלית",

volume = "6",

pages = "287--290",

journal = "High Pressure Research",

issn = "0895-7959",

publisher = "Taylor and Francis Ltd.",

number = "5",

}

TY - JOUR

T1 - Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

AU - Meyerstein, Dan

AU - Zilbermann, Israel

AU - Cohen, Haim

AU - Eldik, Rudi Van

N1 - Funding Information: The authors gratefully acknowledge support from the German-Israeli Foundation for Scientific Research and Development. RvE also acknowledges financial support from the Deutsche Forschungsgemeinschaft and the Volkswagen-Stiftung. DM wishes to. express his thanks to Mrs Irene Evans for her continued interest and support.

PY - 1991/12

Y1 - 1991/12

N2 - The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.

AB - The pressure dependence of an intramolecular electron-transfer reaction between p-nitrobenzoate and the pentaamminecobalt (III) species was studied with the aid of a combined high-pressure pulse-radiolysis technique. The resulting volume of activation of +7.50.3 cm3mor-1 is ascribed to an intrinsic volume increase due to the reduction of Co(III) to Co(II) and some desolvation of the coordinated ligand during the electron-transfer process. The results are compared with related data obtained using conventional kinetic techniques.

KW - aqueous phase chemistry

KW - electron-transfer

KW - high-pressure pulse-radiolysis

KW - reaction kinetics

UR - http://www.scopus.com/inward/record.url?scp=0342679936&partnerID=8YFLogxK

U2 - 10.1080/08957959108203213

DO - 10.1080/08957959108203213

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0342679936

SN - 0895-7959

VL - 6

SP - 287

EP - 290

JO - High Pressure Research

JF - High Pressure Research

IS - 5

ER -

Effect Of Pressure On An Intramolecular Electron-Transfer Reaction Induced By Pulse-R Adioly Sis

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this