Effect of pH on ceria-silica interactions during chemical mechanical polishing

Jeremiah T. Abiade, Wonseop Choi, Rajiv K. Singh

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

To understand the ceria-silica chemical mechanical polishing (CMP) mechanisms, we studied the effect of ceria slurry pH on silica removal and surface morphology. Also, in situ friction force measurements were conducted. After polishing; atomic force microscopy, x-ray photoelectron spectroscopy, and scanning electron microscopy were used to quantify the extent of the particle-substrate interaction during CMP. Our results indicate the silica removal by ceria slurries is strongly pH dependent, with the maximum occurring near the isoelectric point of the ceria slurry.

Original languageEnglish
Pages (from-to)1139-1145
Number of pages7
JournalJournal of Materials Research
Volume20
Issue number5
DOIs
StatePublished - May 2005
Externally publishedYes

Funding

The authors acknowledge the financial support of the Particle Engineering Research Center (PERC) at the University of Florida, The National Science Foundation (NSF Grant EEC-94-02989), the Industrial Partners of the PERC for support of this research, Eric Lambers of the Major Analytical Instrumentation Center, Department of Materials Science and Engineering, University of Florida (Gainesville, FL), and Joodong Park, University of Florida (Gainesville, FL), for assistance with FESEM imaging.

FundersFunder number
Department of Materials Science and Engineering, University of Florida
Joodong Park
PERC
National Science FoundationEEC-94-02989
University of Florida

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