Dynamic topomerization of Cu(I)-complexed pseudorotaxanes

Meera Mohankumar; Michel Holler; Michel Schmitt; Jean Pierre Sauvage; Jean François Nierengarten

doi:10.1039/c2cc37724a

Dynamic topomerization of Cu(I)-complexed pseudorotaxanes

Meera Mohankumar
, Michel Holler
, Michel Schmitt
, Jean Pierre Sauvage
, Jean François Nierengarten

Université de Strasbourg

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Dynamic molecular motions resulting from the folding of a flexible macrocyclic component in a Cu(I)-complexed pseudorotaxane have been evidenced by variable temperature NMR experiments. The proposed conformational changes are also supported by the X-ray crystal structures of the compounds and computational studies.

Original language	English
Pages (from-to)	1261-1263
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	13
DOIs	https://doi.org/10.1039/c2cc37724a
State	Published - 14 Feb 2013
Externally published	Yes

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title = "Dynamic topomerization of Cu(I)-complexed pseudorotaxanes",

abstract = "Dynamic molecular motions resulting from the folding of a flexible macrocyclic component in a Cu(I)-complexed pseudorotaxane have been evidenced by variable temperature NMR experiments. The proposed conformational changes are also supported by the X-ray crystal structures of the compounds and computational studies.",

author = "Meera Mohankumar and Michel Holler and Michel Schmitt and Sauvage, \{Jean Pierre\} and Nierengarten, \{Jean Fran{\c c}ois\}",

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AU - Mohankumar, Meera

AU - Holler, Michel

AU - Schmitt, Michel

AU - Sauvage, Jean Pierre

AU - Nierengarten, Jean François

PY - 2013/2/14

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N2 - Dynamic molecular motions resulting from the folding of a flexible macrocyclic component in a Cu(I)-complexed pseudorotaxane have been evidenced by variable temperature NMR experiments. The proposed conformational changes are also supported by the X-ray crystal structures of the compounds and computational studies.

AB - Dynamic molecular motions resulting from the folding of a flexible macrocyclic component in a Cu(I)-complexed pseudorotaxane have been evidenced by variable temperature NMR experiments. The proposed conformational changes are also supported by the X-ray crystal structures of the compounds and computational studies.

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Dynamic topomerization of Cu(I)-complexed pseudorotaxanes

Abstract

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