Double-Sheet Vanadium Oxide as a Cathode Material for Calcium-Ion Batteries

Munseok S. Chae; Jongwook W. Heo; Jooeun Hyoung; Seung Tae Hong

doi:10.1002/cnma.202000011

Double-Sheet Vanadium Oxide as a Cathode Material for Calcium-Ion Batteries

Munseok S. Chae, Jongwook W. Heo, Jooeun Hyoung, Seung Tae Hong

Daegu Gyeongbuk Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Calcium-ion batteries (CIBs) are theoretically considered one of the potential post-lithium-ion battery technologies. However, only a few host materials are known to intercalate Ca ions. Herein, we demonstrate the use of double-sheet vanadium oxide V₂O₅ ⋅ 0.63H₂O as a high-performance cathode material for CIBs. The vanadium oxide was synthesized via an electrochemical oxidation process on a graphite foil substrate. The material exhibited a high reversible capacity of 204 mAh g⁻¹ at a 0.1 C rate in an aqueous electrolyte, with an average discharge voltage of 2.76 V vs. Ca/Ca²⁺, and a capacity retention of 86% after 350 cycles. The reaction mechanism can be described as a combination of diffusion-controlled intercalation and surface-limited pseudo-capacitance reactions. This study provides a new type of Ca host material, motivating further development of new CIB cathode materials.

Original language	English
Pages (from-to)	1049-1053
Number of pages	5
Journal	ChemNanoMat
Volume	6
Issue number	7
DOIs	https://doi.org/10.1002/cnma.202000011
State	Published - 1 Jul 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

This work was supported by the Samsung Research Funding & Incubation Center of Samsung Electronics under Project Number SRFC‐MA1601‐04.

Funders	Funder number
Samsung	SRFC‐MA1601‐04

Keywords

bi-layered vanadium oxide
calcium intercalation
calcium-ion battery
double-sheet vanadium oxide
multivalent-ion battery

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/cnma.202000011

Cite this

@article{c43ffc1c0ad944109f0d6038fbce32b9,

title = "Double-Sheet Vanadium Oxide as a Cathode Material for Calcium-Ion Batteries",

abstract = "Calcium-ion batteries (CIBs) are theoretically considered one of the potential post-lithium-ion battery technologies. However, only a few host materials are known to intercalate Ca ions. Herein, we demonstrate the use of double-sheet vanadium oxide V2O5 ⋅ 0.63H2O as a high-performance cathode material for CIBs. The vanadium oxide was synthesized via an electrochemical oxidation process on a graphite foil substrate. The material exhibited a high reversible capacity of 204 mAh g−1 at a 0.1 C rate in an aqueous electrolyte, with an average discharge voltage of 2.76 V vs. Ca/Ca2+, and a capacity retention of 86% after 350 cycles. The reaction mechanism can be described as a combination of diffusion-controlled intercalation and surface-limited pseudo-capacitance reactions. This study provides a new type of Ca host material, motivating further development of new CIB cathode materials.",

keywords = "bi-layered vanadium oxide, calcium intercalation, calcium-ion battery, double-sheet vanadium oxide, multivalent-ion battery",

author = "Chae, {Munseok S.} and Heo, {Jongwook W.} and Jooeun Hyoung and Hong, {Seung Tae}",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2020",

month = jul,

day = "1",

doi = "10.1002/cnma.202000011",

language = "אנגלית",

volume = "6",

pages = "1049--1053",

journal = "ChemNanoMat",

issn = "2199-692X",

publisher = "Wiley-VCH Verlag",

number = "7",

}

TY - JOUR

T1 - Double-Sheet Vanadium Oxide as a Cathode Material for Calcium-Ion Batteries

AU - Chae, Munseok S.

AU - Heo, Jongwook W.

AU - Hyoung, Jooeun

AU - Hong, Seung Tae

PY - 2020/7/1

Y1 - 2020/7/1

N2 - Calcium-ion batteries (CIBs) are theoretically considered one of the potential post-lithium-ion battery technologies. However, only a few host materials are known to intercalate Ca ions. Herein, we demonstrate the use of double-sheet vanadium oxide V2O5 ⋅ 0.63H2O as a high-performance cathode material for CIBs. The vanadium oxide was synthesized via an electrochemical oxidation process on a graphite foil substrate. The material exhibited a high reversible capacity of 204 mAh g−1 at a 0.1 C rate in an aqueous electrolyte, with an average discharge voltage of 2.76 V vs. Ca/Ca2+, and a capacity retention of 86% after 350 cycles. The reaction mechanism can be described as a combination of diffusion-controlled intercalation and surface-limited pseudo-capacitance reactions. This study provides a new type of Ca host material, motivating further development of new CIB cathode materials.

AB - Calcium-ion batteries (CIBs) are theoretically considered one of the potential post-lithium-ion battery technologies. However, only a few host materials are known to intercalate Ca ions. Herein, we demonstrate the use of double-sheet vanadium oxide V2O5 ⋅ 0.63H2O as a high-performance cathode material for CIBs. The vanadium oxide was synthesized via an electrochemical oxidation process on a graphite foil substrate. The material exhibited a high reversible capacity of 204 mAh g−1 at a 0.1 C rate in an aqueous electrolyte, with an average discharge voltage of 2.76 V vs. Ca/Ca2+, and a capacity retention of 86% after 350 cycles. The reaction mechanism can be described as a combination of diffusion-controlled intercalation and surface-limited pseudo-capacitance reactions. This study provides a new type of Ca host material, motivating further development of new CIB cathode materials.

KW - bi-layered vanadium oxide

KW - calcium intercalation

KW - calcium-ion battery

KW - double-sheet vanadium oxide

KW - multivalent-ion battery

UR - http://www.scopus.com/inward/record.url?scp=85085569816&partnerID=8YFLogxK

U2 - 10.1002/cnma.202000011

DO - 10.1002/cnma.202000011

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:85085569816

SN - 2199-692X

VL - 6

SP - 1049

EP - 1053

JO - ChemNanoMat

JF - ChemNanoMat

IS - 7

ER -

Double-Sheet Vanadium Oxide as a Cathode Material for Calcium-Ion Batteries

Abstract

Bibliographical note

Funding

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this