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Direct and indirect electron emission from the green fluorescent protein chromophore

  • Y. Toker
  • , D. B. Rahbek
  • , B. Klærke
  • , A. V. Bochenkova
  • , L. H. Andersen
  • Aarhus University

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Photoelectron spectra of the deprotonated green fluorescent protein chromophore have been measured in the gas phase at several wavelengths within and beyond the S 0-S 1 photoabsorption band of the molecule. The vertical detachment energy (VDE) was determined to be 2.68±0.1eV. The data show that the first electronically excited state is bound in the Franck-Condon region, and that electron emission proceeds through an indirect (resonant) electron-emission channel within the corresponding absorption band.

Original languageEnglish
Article number128101
JournalPhysical Review Letters
Volume109
Issue number12
DOIs
StatePublished - 18 Sep 2012
Externally publishedYes

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