Development in SmI2 Catalyzed Reactions

Sandeepan Maity

doi:10.1002/ejoc.202100962

Development in SmI₂ Catalyzed Reactions

Sandeepan Maity

Invertis University

Research output: Contribution to journal › Review article › peer-review

8 Scopus citations

Abstract

Samarium diiodide (SmI₂) is a versatile single electron transfer (SET) reagent in organic synthesis. The advantages of SmI₂ arise from various additive induced tailoring of reactions to obtain the desired products in a stereoselective fashion. In most instances, this reagent is used in stoichiometric amount, and this poses a significant environmental issue limiting a broader applicability of SmI₂. Despite challenges in the developments of catalytic methods, recent studies have paved the way for catalytic strategies rejuvenating the applications of SmI₂ in synthetic organic chemistry. This review aims to summarize different methods that are used to develop catalytic reactions of SmI₂. A comparison of different approaches and future outlook of this field are discussed.

Original language	English
Pages (from-to)	5312-5319
Number of pages	8
Journal	European Journal of Organic Chemistry
Volume	2021
Issue number	37
DOIs	https://doi.org/10.1002/ejoc.202100962
State	Published - 7 Oct 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 Wiley-VCH GmbH

Funding

The author of this article thanks Dr. Avik Kumar Pati and Dr. Lalit Kumar for providing valuable suggestions in preparing the manuscript.

Keywords

Electrochemistry
Electron transfer
Lanthanides
Radical reactions
Reaction mechanism

Access to Document

10.1002/ejoc.202100962

Cite this

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KW - Radical reactions

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