DESCRIPTION OF THE SPECIFIC ADSORPTION OF IONS ON A POLYCRYSTALLINE ELECTRODE ACCORDING TO THE MODEL OF A SINGLE DIFFUSE LAYER.

M. D. Levi, B. B. Damaskin

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Abstract

Expressions for the relationship between the absorption parameters of polycrystalline electrode and individual single-crystal faces have been obtained according to the model of a single diffuse layer. The plots of the dependence of the potential jump in the compact part of the double layer on the number of specifically adsorbed ions calculated according to this model are linear, just as in the case of electrodes with a homogeneous surface. It is shown that the virial isotherm with a correction for the PSI o potential can serve as a criterion for establishing an adequate model of an interface between a polycrystalline electrode and a solution of a surface-active electrolyte.

Original languageEnglish
Pages (from-to)515-520
Number of pages6
JournalSoviet electrochemistry
Volume19
Issue number5
StatePublished - 1983

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