Stereoselective Synthesis of Functionalized Pyrrolidines via Intramolecular 1,3-Dipolar Silyl Nitronate Cycloaddition

Levi Gottlieb, Alfred Hassner

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

Michael addition products of secondary allylamines to nitroalkenes were captured as the O-silyl α-allylaminoalkylnitronates. These undergo stereoselective intramolecular silyl nitronate-olefin 1,3-dipolar cycloaddition to provide highly functionalized pyrrolidines.

Original languageEnglish
Pages (from-to)3759-3763
Number of pages5
JournalJournal of Organic Chemistry
Volume60
Issue number12
DOIs
StatePublished - 1 Jun 1995

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