Abstract
The foundations of the fractional diffusion equation are investigated based on coupled and decoupled continuous time random walks (CTRW). For this aim we find an exact solution of the decoupled CTRW, in terms of an infinite sum of stable probability densities. This exact solution is then used to understand the meaning and domain of validity of the fractional diffusion equation. An interesting behavior is discussed for coupled memories (i.e., Lévy walks). The moments of the random walk exhibit strong anomalous diffusion, indicating (in a naive way) the breakdown of simple scaling behavior and hence of the fractional approximation. Still the Green function P(x, t) is described well by the fractional diffusion equation, in the long time limit.
Original language | English |
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Pages (from-to) | 13-27 |
Number of pages | 15 |
Journal | Chemical Physics |
Volume | 284 |
Issue number | 1-2 |
DOIs | |
State | Published - 1 Nov 2002 |
Externally published | Yes |
Bibliographical note
Funding Information:This research was supported in part by a grant from the NSF. I thank A.I. Saichev and G. Zumofen for helpful correspondence and R. Silbey for comments on the manuscript.
Funding
This research was supported in part by a grant from the NSF. I thank A.I. Saichev and G. Zumofen for helpful correspondence and R. Silbey for comments on the manuscript.
Funders | Funder number |
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National Science Foundation |