Covalent binding of a nickel macrocyclic complex to a silica support: Towards an electron exchange column

Smadar Attia, Alexander Shames, Israel Zilbermann, Gil Goobes, Eric Maimon, Dan Meyerstein

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Ni(ii)L2, L2 = 1-propyl-1,3,5,8,12- pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(iii) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

Original languageEnglish
Pages (from-to)103-110
Number of pages8
JournalDalton Transactions
Volume43
Issue number1
DOIs
StatePublished - 7 Jan 2014

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