Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

Amihai Eisenstadt; Rina Tannenbaum; Avi Efraty

doi:10.1016/s0022-328x(00)88373-4

Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

Amihai Eisenstadt, Rina Tannenbaum, Avi Efraty

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The reactions of [CpRu(CO)₂]₂ with CX₄ (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)₂X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)₂H, prepared "in situ" from Ru₃(CO)₁₂ and cyclopentadiene, with CX₄ (X = Cl, Br).

Original language	English
Pages (from-to)	317-321
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	221
Issue number	3
DOIs	https://doi.org/10.1016/s0022-328x(00)88373-4
State	Published - 8 Dec 1981
Externally published	Yes

Bibliographical note

Funding Information:
a grant from the U.S.-Israel Bina-

Funding Information:
This research program was supported tional Science Foundations.

Funding

a grant from the U.S.-Israel Bina- This research program was supported tional Science Foundations.

Funders	Funder number
Science Foundations
U.S.-Israel Bina

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title = "Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide",

abstract = "The reactions of [CpRu(CO)2]2 with CX4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)2H, prepared {"}in situ{"} from Ru3(CO)12 and cyclopentadiene, with CX4 (X = Cl, Br).",

author = "Amihai Eisenstadt and Rina Tannenbaum and Avi Efraty",

note = "Funding Information: a grant from the U.S.-Israel Bina- Funding Information: This research program was supported tional Science Foundations.",

year = "1981",

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doi = "10.1016/s0022-328x(00)88373-4",

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issn = "0022-328X",

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T1 - Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

AU - Eisenstadt, Amihai

AU - Tannenbaum, Rina

AU - Efraty, Avi

N1 - Funding Information: a grant from the U.S.-Israel Bina- Funding Information: This research program was supported tional Science Foundations.

PY - 1981/12/8

Y1 - 1981/12/8

N2 - The reactions of [CpRu(CO)2]2 with CX4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)2H, prepared "in situ" from Ru3(CO)12 and cyclopentadiene, with CX4 (X = Cl, Br).

AB - The reactions of [CpRu(CO)2]2 with CX4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO)2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO)2H, prepared "in situ" from Ru3(CO)12 and cyclopentadiene, with CX4 (X = Cl, Br).

UR - https://www.scopus.com/pages/publications/0000857346

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VL - 221

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Convenient synthetic routes to the cyclopentadienylruthenium dicarbonyl chloride and bromide

Abstract

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