Abstract
Construction of synthetic macrocyclic host that can bind with neutral molecules and anions has potential applications in supramolecular chemistry. Herein, we have designed and synthesized blue light emitting an unsymmetrical neutral bis‐urea macrocyclic host. This macrocycle can bind with neutral DMF molecule (1:1) as well as Cl− ion (1:1) through noncovalent interactions. X‐Ray crystal structure, 1H NMR titrations with Job's Plot, HRMS with isotropic distribution pattern, FT‐IR, and density functional theory analysis revealed the binding of bis‐urea macrocyclic host with the guest molecule.
| Original language | English |
|---|---|
| Pages (from-to) | 2033-2038 |
| Number of pages | 6 |
| Journal | Journal of Heterocyclic Chemistry |
| Volume | 58 |
| Issue number | 10 |
| DOIs | |
| State | Published - Oct 2021 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2021 Wiley Periodicals LLC.
Funding
Science and Engineering Research BoardECR/2017/001405 Funding information Science and Engineering Research Board, Grant/Award Number: ECR/2017/001405 This work is supported by grants from the DST‐SERB, Govt. of India (file no. ECR/2017/001405).
| Funders | Funder number |
|---|---|
| DST‐SERB | |
| Science and Engineering Research BoardECR/2017/001405 Funding information Science and Engineering Research Board | ECR/2017/001405 |