TY - JOUR
T1 - Conflicting evidence regarding the mechanism of the sulfonyl transfer reaction
AU - Hoz, Shmaryahu
AU - Liu, Ping
AU - Buncel, Erwin
PY - 1996
Y1 - 1996
N2 - Application of the novel solvent-dependent pKa method for the construction of Brønsted-type plots to the sulfonyl transfer reaction with phenoxide nucleophiles, finds the pKa's of aryloxides lower than those of the p-nitrophenoxide leaving group on separate lines, whereas nucleophiles of greater pKa fall on a common line, contrasting with the observed behaviour when using the traditional method.
AB - Application of the novel solvent-dependent pKa method for the construction of Brønsted-type plots to the sulfonyl transfer reaction with phenoxide nucleophiles, finds the pKa's of aryloxides lower than those of the p-nitrophenoxide leaving group on separate lines, whereas nucleophiles of greater pKa fall on a common line, contrasting with the observed behaviour when using the traditional method.
UR - https://www.scopus.com/pages/publications/0040958167
U2 - 10.1039/cc9960000995
DO - 10.1039/cc9960000995
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AN - SCOPUS:0040958167
SN - 1359-7345
SP - 995
EP - 996
JO - Chemical Communications
JF - Chemical Communications
IS - 8
ER -