Cleavage vs. Beckmann Rearrangement in α-Oximino Ketones

Alfred Hassner; W. A. Wentworth; I. H. Pomerantz

doi:10.1021/jo01037a006

Cleavage vs. Beckmann Rearrangement in α-Oximino Ketones

Alfred Hassner
, W. A. Wentworth
, I. H. Pomerantz

University of Colorado Boulder

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Certain cyclic α-oximino ketones under Beckmann rearrangement conditions yield the expected rearrangement products (imides), but it can be shown that the reaction proceeds first by cleavage followed by ring closure to the imides.

Original language	English
Pages (from-to)	304-306
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	28
Issue number	2
DOIs	https://doi.org/10.1021/jo01037a006
State	Published - 1 Feb 1963
Externally published	Yes

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title = "Cleavage vs. Beckmann Rearrangement in α-Oximino Ketones",

abstract = "Certain cyclic α-oximino ketones under Beckmann rearrangement conditions yield the expected rearrangement products (imides), but it can be shown that the reaction proceeds first by cleavage followed by ring closure to the imides.",

author = "Alfred Hassner and Wentworth, \{W. A.\} and Pomerantz, \{I. H.\}",

year = "1963",

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doi = "10.1021/jo01037a006",

language = "אנגלית",

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N2 - Certain cyclic α-oximino ketones under Beckmann rearrangement conditions yield the expected rearrangement products (imides), but it can be shown that the reaction proceeds first by cleavage followed by ring closure to the imides.

AB - Certain cyclic α-oximino ketones under Beckmann rearrangement conditions yield the expected rearrangement products (imides), but it can be shown that the reaction proceeds first by cleavage followed by ring closure to the imides.

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AN - SCOPUS:0000028069

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EP - 306

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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Cleavage vs. Beckmann Rearrangement in α-Oximino Ketones

Abstract

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