Chiral Trifluoro Diamines as Convenient Reagents for Determining the Enantiomeric Purity of Aldehydes by Use of 19F NMR Spectroscopy

David Cuvinot; Pierre Mangeney; Alexandre Alexakis; Jean F. Normant; Jean Paul Lellouche

doi:10.1021/jo00271a034

Chiral Trifluoro Diamines as Convenient Reagents for Determining the Enantiomeric Purity of Aldehydes by Use of ¹⁹F NMR Spectroscopy

David Cuvinot
, Pierre Mangeney
, Alexandre Alexakis
, Jean F. Normant
, Jean Paul Lellouche

Sorbonne Université
Serv. des Molecules Marquees

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

N,N '-Dimethyl-l,2-bis[o-, m-, and p-(trifluoromethyl)phenyl]-l,2-ethanediamines have been prepared. The meta trifluoro diamine was used as a chiral reagent for determining the enantiomeric purity of chiral aldehydes.

Original language	English
Pages (from-to)	2420-2425
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	54
Issue number	10
DOIs	https://doi.org/10.1021/jo00271a034
State	Published - 1 May 1989
Externally published	Yes

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title = "Chiral Trifluoro Diamines as Convenient Reagents for Determining the Enantiomeric Purity of Aldehydes by Use of 19F NMR Spectroscopy",

abstract = "N,N '-Dimethyl-l,2-bis[o-, m-, and p-(trifluoromethyl)phenyl]-l,2-ethanediamines have been prepared. The meta trifluoro diamine was used as a chiral reagent for determining the enantiomeric purity of chiral aldehydes.",

author = "David Cuvinot and Pierre Mangeney and Alexandre Alexakis and Normant, \{Jean F.\} and Lellouche, \{Jean Paul\}",

year = "1989",

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T1 - Chiral Trifluoro Diamines as Convenient Reagents for Determining the Enantiomeric Purity of Aldehydes by Use of 19F NMR Spectroscopy

AU - Cuvinot, David

AU - Mangeney, Pierre

AU - Alexakis, Alexandre

AU - Normant, Jean F.

AU - Lellouche, Jean Paul

PY - 1989/5/1

Y1 - 1989/5/1

N2 - N,N '-Dimethyl-l,2-bis[o-, m-, and p-(trifluoromethyl)phenyl]-l,2-ethanediamines have been prepared. The meta trifluoro diamine was used as a chiral reagent for determining the enantiomeric purity of chiral aldehydes.

AB - N,N '-Dimethyl-l,2-bis[o-, m-, and p-(trifluoromethyl)phenyl]-l,2-ethanediamines have been prepared. The meta trifluoro diamine was used as a chiral reagent for determining the enantiomeric purity of chiral aldehydes.

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U2 - 10.1021/jo00271a034

DO - 10.1021/jo00271a034

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 10

ER -

Chiral Trifluoro Diamines as Convenient Reagents for Determining the Enantiomeric Purity of Aldehydes by Use of ¹⁹F NMR Spectroscopy

Abstract

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