Catalytic transformation of carbon black to carbon nanotubes

Stanislav Kishinevsky; Sergey I. Nikitenko; David M. Pickup; Ernst R.H. Van-Eck; Aharon Gedanken

doi:10.1021/cm025598j

Catalytic transformation of carbon black to carbon nanotubes

Stanislav Kishinevsky
, Sergey I. Nikitenko
, David M. Pickup
, Ernst R.H. Van-Eck
, Aharon Gedanken

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

We report here a novel method of catalytic transformation of amorphous carbon to CNT. The method involves Fe(CO)₅ thermolysis in the presence of carbon black at high pressure. A mechanism is proposed; it is verified by solid-state NMR measurements.

Original language	English
Pages (from-to)	4498-4501
Number of pages	4
Journal	Chemistry of Materials
Volume	14
Issue number	11
DOIs	https://doi.org/10.1021/cm025598j
State	Published - 1 Nov 2002

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title = "Catalytic transformation of carbon black to carbon nanotubes",

abstract = "We report here a novel method of catalytic transformation of amorphous carbon to CNT. The method involves Fe(CO)5 thermolysis in the presence of carbon black at high pressure. A mechanism is proposed; it is verified by solid-state NMR measurements.",

author = "Stanislav Kishinevsky and Nikitenko, \{Sergey I.\} and Pickup, \{David M.\} and Van-Eck, \{Ernst R.H.\} and Aharon Gedanken",

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AU - Kishinevsky, Stanislav

AU - Nikitenko, Sergey I.

AU - Pickup, David M.

AU - Van-Eck, Ernst R.H.

AU - Gedanken, Aharon

PY - 2002/11/1

Y1 - 2002/11/1

N2 - We report here a novel method of catalytic transformation of amorphous carbon to CNT. The method involves Fe(CO)5 thermolysis in the presence of carbon black at high pressure. A mechanism is proposed; it is verified by solid-state NMR measurements.

AB - We report here a novel method of catalytic transformation of amorphous carbon to CNT. The method involves Fe(CO)5 thermolysis in the presence of carbon black at high pressure. A mechanism is proposed; it is verified by solid-state NMR measurements.

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JO - Chemistry of Materials

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Catalytic transformation of carbon black to carbon nanotubes

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