Catalytic aerobic oxidation of cycloalkanes with nanostructured amorphous metals and alloys

Venkitasamy Kesavan; Pennadam S. Sivanand; Srinivasan Chandrasekaran; Yuri Koltypin; Aharon Gedanken

doi:10.1002/(SICI)1521-3773(19991203)38:23<3521::AID-ANIE3521>3.0.CO;2-S

Catalytic aerobic oxidation of cycloalkanes with nanostructured amorphous metals and alloys

Venkitasamy Kesavan
, Pennadam S. Sivanand
, Srinivasan Chandrasekaran
, Yuri Koltypin
, Aharon Gedanken

Department of Chemistry

Indian Institute of Science Bangalore

Research output: Contribution to journal › Article › peer-review

115 Scopus citations

Abstract

Under mild conditions (40 atm O2, 28°C, 10-15 h), an efficient aerobic oxidation of cycloalkanes to cycloalkanols can be achieved using nanostructured amorphous metals such as Fe and Co and an amorphous alloy like Fe₂₀Ni₈₀ as catalysts. For example, cyclohexane is oxidized to cyclohexanol with 32-41% conversion, while 1-adamantanol is formed from adamantane with 52-57% conversion.

Original language	English
Pages (from-to)	3521-3523
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	23
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19991203)38:23<3521::AID-ANIE3521>3.0.CO;2-S
State	Published - 3 Dec 1999

Keywords

Alkanes
C-H activation
Catalysts
Nanostructures
Oxidations

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10.1002/(SICI)1521-3773(19991203)38:23<3521::AID-ANIE3521>3.0.CO;2-S

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title = "Catalytic aerobic oxidation of cycloalkanes with nanostructured amorphous metals and alloys",

abstract = "Under mild conditions (40 atm O2, 28°C, 10-15 h), an efficient aerobic oxidation of cycloalkanes to cycloalkanols can be achieved using nanostructured amorphous metals such as Fe and Co and an amorphous alloy like Fe20Ni80 as catalysts. For example, cyclohexane is oxidized to cyclohexanol with 32-41\% conversion, while 1-adamantanol is formed from adamantane with 52-57\% conversion.",

keywords = "Alkanes, C-H activation, Catalysts, Nanostructures, Oxidations",

author = "Venkitasamy Kesavan and Sivanand, \{Pennadam S.\} and Srinivasan Chandrasekaran and Yuri Koltypin and Aharon Gedanken",

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T1 - Catalytic aerobic oxidation of cycloalkanes with nanostructured amorphous metals and alloys

AU - Kesavan, Venkitasamy

AU - Sivanand, Pennadam S.

AU - Chandrasekaran, Srinivasan

AU - Koltypin, Yuri

AU - Gedanken, Aharon

PY - 1999/12/3

Y1 - 1999/12/3

N2 - Under mild conditions (40 atm O2, 28°C, 10-15 h), an efficient aerobic oxidation of cycloalkanes to cycloalkanols can be achieved using nanostructured amorphous metals such as Fe and Co and an amorphous alloy like Fe20Ni80 as catalysts. For example, cyclohexane is oxidized to cyclohexanol with 32-41% conversion, while 1-adamantanol is formed from adamantane with 52-57% conversion.

AB - Under mild conditions (40 atm O2, 28°C, 10-15 h), an efficient aerobic oxidation of cycloalkanes to cycloalkanols can be achieved using nanostructured amorphous metals such as Fe and Co and an amorphous alloy like Fe20Ni80 as catalysts. For example, cyclohexane is oxidized to cyclohexanol with 32-41% conversion, while 1-adamantanol is formed from adamantane with 52-57% conversion.

KW - Alkanes

KW - C-H activation

KW - Catalysts

KW - Nanostructures

KW - Oxidations

UR - https://www.scopus.com/pages/publications/0033521190

U2 - 10.1002/(SICI)1521-3773(19991203)38:23<3521::AID-ANIE3521>3.0.CO;2-S

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AN - SCOPUS:0033521190

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

ER -

Catalytic aerobic oxidation of cycloalkanes with nanostructured amorphous metals and alloys

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