Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

Shlomo Margel; Fred C. Anson

doi:10.1149/1.2131655

Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

Shlomo Margel
, Fred C. Anson

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.

Original language	English
Pages (from-to)	1232-1235
Number of pages	4
Journal	Journal of the Electrochemical Society
Volume	125
Issue number	8
DOIs	https://doi.org/10.1149/1.2131655
State	Published - Aug 1978
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

catalysis
intramolecular
π-coordination

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10.1149/1.2131655

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title = "Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes",

abstract = "The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.",

keywords = "catalysis, intramolecular, π-coordination",

author = "Shlomo Margel and Anson, \{Fred C.\}",

year = "1978",

month = aug,

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journal = "Journal of the Electrochemical Society",

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T1 - Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

AU - Margel, Shlomo

AU - Anson, Fred C.

PY - 1978/8

Y1 - 1978/8

N2 - The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.

AB - The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.

KW - catalysis

KW - intramolecular

KW - π-coordination

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U2 - 10.1149/1.2131655

DO - 10.1149/1.2131655

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AN - SCOPUS:0018004930

SN - 0013-4651

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SP - 1232

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JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

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ER -

Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

Abstract

UN SDGs

Keywords

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