Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

Shlomo Margel; Fred C. Anson

doi:10.1149/1.2131655

Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

Shlomo Margel, Fred C. Anson

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.

Original language	English
Pages (from-to)	1232-1235
Number of pages	4
Journal	Journal of the Electrochemical Society
Volume	125
Issue number	8
DOIs	https://doi.org/10.1149/1.2131655
State	Published - Aug 1978
Externally published	Yes

Keywords

catalysis
intramolecular
π-coordination

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1149/1.2131655

Cite this

@article{5211cf32691c4eba88e56ed08dd93fb0,

title = "Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes",

abstract = "The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.",

keywords = "catalysis, intramolecular, π-coordination",

author = "Shlomo Margel and Anson, {Fred C.}",

year = "1978",

month = aug,

doi = "10.1149/1.2131655",

language = "אנגלית",

volume = "125",

pages = "1232--1235",

journal = "Journal of the Electrochemical Society",

issn = "0013-4651",

publisher = "Institute of Physics",

number = "8",

}

TY - JOUR

T1 - Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

AU - Margel, Shlomo

AU - Anson, Fred C.

PY - 1978/8

Y1 - 1978/8

N2 - The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.

AB - The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′-bipyridine. A prominent reaction product of the catalyzed reduction is 1,5-hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt-2,2′-bipyridine complexes.

KW - catalysis

KW - intramolecular

KW - π-coordination

UR - http://www.scopus.com/inward/record.url?scp=0018004930&partnerID=8YFLogxK

U2 - 10.1149/1.2131655

DO - 10.1149/1.2131655

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0018004930

SN - 0013-4651

VL - 125

SP - 1232

EP - 1235

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

IS - 8

ER -

Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′-Bipyridine Complexes

Abstract

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this