Can ground-state destabilization of an α-nucleophile induce an α-effect?

Erwin Buncel; Shmaryahu Hoz

doi:10.1016/S0040-4039(00)94005-X

Can ground-state destabilization of an α-nucleophile induce an α-effect?

Erwin Buncel, Shmaryahu Hoz

Department of Chemistry

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41 Scopus citations

Abstract

The possible importance of ground-state destabilization as the origin of the enhanced reactivity of α-nucleophiles is critically examined and it is concluded that, in general, this factor will contribute only slightly, if at all, to the manifestation of α-effects.

Original language	English
Pages (from-to)	4777-4780
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	44
DOIs	https://doi.org/10.1016/S0040-4039(00)94005-X
State	Published - 1983

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10.1016/S0040-4039(00)94005-X

Cite this

@article{e41ce1e614564049ab4406a62e7fc1fd,

title = "Can ground-state destabilization of an α-nucleophile induce an α-effect?",

abstract = "The possible importance of ground-state destabilization as the origin of the enhanced reactivity of α-nucleophiles is critically examined and it is concluded that, in general, this factor will contribute only slightly, if at all, to the manifestation of α-effects.",

author = "Erwin Buncel and Shmaryahu Hoz",

year = "1983",

doi = "10.1016/S0040-4039(00)94005-X",

language = "אנגלית",

volume = "24",

pages = "4777--4780",

journal = "Tetrahedron Letters",

issn = "0040-4039",