Abstract
A new approach to nanostructure formation based on replication of an existing pattern of colloidal Au nanoparticles is described. The key steps in this strategy involve the coating of a well-defined Au colloid monolayer with an SiOx sol-gel, HF etching until colloidal particles are exposed, and removal of colloidal Au with aqua regia. This process was carried out on a two-dimensional array of 12nm diameter particles on an In-doped SnO2 (ITO) substrate, and monitored by UV-vis, electrochemistry, and atomic force microscopy (AFM). AFM data indicate the strategy is feasible, with clearly visible differences in surface morphology observed between bare ITO and colloidal Au-depleted, SiOx-coated ITO.
Original language | English |
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Pages (from-to) | 147-154 |
Number of pages | 8 |
Journal | Supramolecular Science |
Volume | 4 |
Issue number | 1-2 |
DOIs | |
State | Published - 1997 |
Externally published | Yes |
Bibliographical note
Funding Information:We acknowledgep artial support of this work from the Beckman Foundation and from the National Science Foundation (CHE-9256692)A. cknowledgemenits also made to the Electron Microscopy Facility for the Life Sciencesin the BiotechnologyI nstitutea t The Pennsylvania StateU niversity.W e thank Andy Hooper of the Allara group for XPS spectra.
Funding
We acknowledgep artial support of this work from the Beckman Foundation and from the National Science Foundation (CHE-9256692)A. cknowledgemenits also made to the Electron Microscopy Facility for the Life Sciencesin the BiotechnologyI nstitutea t The Pennsylvania StateU niversity.W e thank Andy Hooper of the Allara group for XPS spectra.
Funders | Funder number |
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Beckman Foundation | |
National Science Foundation | CHE-9256692 |